What materials can be used in 3d printers

• Plastic is still the most popular material used for 3D printing.
• As the 3D-printing market value increases, the list of what materials can be used also grows.
• Raw materials such as metal, graphite, and carbon fiber are commonly used for 3D printing, though at-home use is mostly limited to PLA for now.

Ice cream. Molecules for medicine. Even human skin. The list of what materials are used in 3D printing grows longer—and much more interesting—by the day. And expanding it is a multibillion-dollar material arms race right now.

A recently released 3D-printing market study found that the worldwide market for 3D-printing products was valued at $12. 6 billion in 2020 and was expected to grow to $37.2 billion by 2036. That means a huge increase in the materials those machines use.

What Is The Most Common Material Used for 3D Printing?

Plastic still reigns supreme in the 3D printing. According to a Grand View Research report, the market size for 3D printing plastics globally was valued at $638.7 million in 2020 and was expected to grow to $2.83 billion by 2027.

This material isn’t just your “everyday” plastic. Two types of plastic are most commonly used in 3D printing:

• PLA: Poly Lactic Acid (PLA) is the most popular 3D-printing material. It’s a biodegradable plastic made from renewables such as cornstarch. Its low melting point makes it easy to use at home.
• ABS: Acrylonitrile butadiene styrene (ABS) is best suited for parts that require strength and flexibility, like car components or household appliances. It’s also known for its low cost.

But it doesn’t stop there in the 3D-printing materials world.

1. Metal

Used for: Ready-to-install parts, finished products, prototypes

If there is a runner-up to plastic, it would be metal. Direct metal laser sintering (DMLS) is the technique and, unlike printing plastics, it can be used to make either a finished industrial product or a prototype. The aviation industry is already an early proponent and consumer of DMLS printing to streamline operations and manufacture ready-to-install parts. There are even already mass-market DMLS printers for creating 3D-printed jewelry.

The growth and popularity of 3D printing metals holds the potential to manufacture and create more effective machine parts that currently cannot be mass-produced onsite. This could lead to better conductors, tensile strength, and other attributes of laboratory metals than “mined-and-refined” metals such as steel and copper.

In the aerospace industry, the materials question is largely answered, and creating volume of parts is the Holy Grail. GE Aviation began printing fuel nozzles for its LEAP jet engine in 2016, ramping up to 30,000 parts in less than three years and printing its 100,000th nozzle in 2021. The LEAP’s successor, the RISE, will also incorporate 3D-printed parts.

Used for: Electronics, lighting

Australian-listed graphite and nickel miner Kibaran Resources has partnered with 3D-printing company 3D Group to share development costs on a research-and-development venture called 3D Graphtech Industries.

The partnership is pursuing patents to investigate 3D printing graphite and graphene, a pure form of carbon first created in a laboratory in 2004. Graphene conducts electricity better and is stronger, easier to insulate, and lighter than other conductors on the market today. It outperforms even the best conductors several times over. Because it must be created in a lab, it is a good case study for just what kind of mass production of metals additive manufacturing can accomplish.

Materials for research and development are sourced from Kibaran’s Tanzanian mines, where graphite with high crystallinity and a purity of 99.9% carbon has been found. This is incredibly well-suited to the production of graphene.

The semiconductor industry is interested in producing large quantities of graphene, as well. For example, IBM found a way to use it for LED lighting in 2014. The ability to 3D print sheets of material for use in LEDs could seriously cut lighting production costs.

Used for: Bearings, parts, electrical cable installation

Related to graphite, carbon fiber (which undergoes an oxidation process that stretches the polymer) can be added to the more traditional plastic to create a composite that can be as strong as steel but less intensive to use than aluminum, says Markforged. The company’s large-format 3D printers are designed to print stronger parts more quickly and at significantly lower costs.

Meanwhile, startup Impossible Objects has also been exploring carbon fiber, as well as glass, Kevlar, and fiberglass. The company’s printer can also work with PEEK (polyether ether ketone) thermoplastic polymers, which are typically used for bearings, piston parts, and electrical cable installation.

New 3D Printing Materials

The 3D-printing industry is experimenting with a wide variety of innovative, novel approaches such a bio-based resins made from corn and soybean oil, powders, nitinol, and even paper.

As the list of materials grows, what does this mean for the actual hardware? Right now, on the consumer level, plastic is about as good as it gets. For example, the $1,399 Dremel 3D40 Flex is limited to PLA.

Today, several printers are focused entirely on DMLS, including the 3DSystems DMP Flex 350 and several models from Stratasys, but these currently cost upward of $100,000 each because DMLS printers burn much hotter than their plastic counterparts, as the powders and metals they create have higher melting points. Stronger housings and more powerful industrial smelting tools increase their costs significantly.

Although many 3D-printer manufacturers are offering metal 3D-printing services, it will be some time before the economies of scale that helped bring down the cost of plastic 3D printing affect the DMLS market. And 3D-printing systems with graphite/carbon fiber are just now starting to gain traction in the marketplace.

The diversity of applications that industries are exploring for 3D printing makes for an exciting but tumultuous time. From jet parts to lighting to rapid prototyping, the new (and “old”) 3D printing materials will deliver even more opportunities for how and what industries print.

This article has been updated. It was originally published in November 2014.

About the Author

Jeff Yoders has covered IT, CAD, and BIM for Building Design + Construction, Structural Engineer, and CE News magazines. He has won six American Society of Business Publications Editors awards and was part of the reporting team for the 2012 Jesse H. Neal Award for best subject-related series of stories.

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What Materials Are Used in the 3D Printing Process?

The materials used for 3D printing are as diverse as the products that result from the process. As such, 3D printing is flexible enough to allow manufacturers to determine the shape, texture and strength of a product. Best of all, these qualities can be achieved with far fewer steps than what is typically required in traditional means of production. Moreover, these products can be made with various types of 3D printing materials.

In order for a 3D print to be realized in the form of a finished product, a detailed image of the design in question must first be submitted to the printer. The details are rendered in standard triangle language (STL), which conveys the intricacies and dimensions of a given design and allows a computerized 3D printer to see a design from all sides and angles.

Basically, an STL design is the equivalent of multiple flat designs in one computerized file.

The industry for 3D printing is expected to surpass the 10-figure mark in the near future and plastic is set to be the main material to drive this market. As concluded recently in a SmarTech Markets Publishing study, the market for 3D printing is likely to exceed $1.4 billion before 2020. With an ongoing market expansion, the industry has sought new ways to yield plastics, including the use of organic ingredients like soybean oil and corn. Consequently, plastics are set to become the most environmentally friendly option in 3D printing.

Plastic

Out of all the raw materials for 3D printing in use today, plastic is the most common. Plastic is one of the most diverse materials for 3D-printed toys and household fixtures. Products made with this technique include desk utensils, vases and action figures. Available in transparent form as well as bright colors — of which red and lime green are particularly popular — plastic filaments are sold on spools and can have either a matte or shiny texture.

With its firmness, flexibility, smoothness and bright range of color options, the appeal of plastic is easy to understand. As a relatively affordable option, plastic is generally light on the pocketbooks of creators and consumers alike.

Plastic products are generally made with FDM printers, in which thermoplastic filaments are melted and molded into shape, layer by layer. The types of plastic used in this process are usually made from one of the following materials:

• Polyastic acid (PLA): One of the eco-friendliest options for 3D printers, polyastic acid is sourced from natural products like sugar cane and corn starch and is therefore biodegradable. Available in soft and hard forms, plastics made from polyastic acid are expected to dominate the 3D printing industry in the coming years. Hard PLA is the stronger and therefore more ideal material for a broader range of products.
• Acrylonitrile butadiene styrene (ABS): Valued for its strength and safety, ABS is a popular option for home-based 3D printers. Alternately referred to as “LEGO plastic,” the material consists of pasta-like filaments that give ABS its firmness and flexibility. ABS is available in various colors that make the material suitable for products like stickers and toys. Increasingly popular among craftspeople, ABC is also used to make jewelry and vases.
• Polyvinyl Alcohol Plastic (PVA): Used in low-end home printers, PVA is a suitable plastic for support materials of the dissolvable variety. Though not suitable for products that require high strength, PVA can be a low-cost option for temporary-use items.
• Polycarbonate (PC): Less frequently used than the aforementioned plastic types, polycarbonate only works in 3D printers that feature nozzle designs and that operate at high temperatures. Among other things, polycarbonate is used to make low-cost plastic fasteners and molding trays.

Plastic items made in 3D printers come in a variety of shapes and consistencies, from flat and round to grooved and meshed. A quick search of Google images will show a novel range of 3D-printed plastic products such as mesh bracelets, cog wheels and Incredible Hulk action figures. For the home craftsperson, polycarbonate spools can now be purchased in bright colors at most supply stores.

Powders

Today’s more state-of-the-art 3D printers use powdered materials to construct products. Inside the printer, the powder is melted and distributed in layers until the desired thickness, texture and patterns are made. The powders can come from various sources and materials, but the most common are:

• Polyamide (Nylon): With its strength and flexibility, polyamide allows for high levels of detail on a 3D-printed product. The material is especially suited for joining pieces and interlocking parts in a 3D-printed model. Polyamide is used to print everything from fasteners and handles to toy cars and figures.
• Alumide: Comprised of a mix of polyamide and gray aluminum, alumide powder makes for some of the strongest 3D-printed models. Recognized by its grainy and sandy appearance, the powder is reliable for industrial models and prototypes.

In powder form, materials like steel, copper and other types of metal are easier to transport and mold into desired shapes. As with the various types of plastic used in 3D printing, metal powder must be heated to the point where it can be distributed layer-by-layer to form a completed shape.

Resins

One of the more limiting and therefore less-used materials in 3D printing is resin. Compared to other 3D-applicable materials, resin offers limited flexibility and strength. Made of liquid polymer, resin reaches its end state with exposure to UV light. Resin is generally found in black, white and transparent varieties, but certain printed items have also been produced in orange, red, blue and green.

The material comes in the following three categories:

• High-detail resins: Generally used for small models that require intricate detail. For example, four-inch figurines with complex wardrobe and facial details are often printed with this grade of resin.
• Paintable resin: Sometimes used in smooth-surface 3D prints, resins in this class are noted for their aesthetic appeal. Figurines with rendered facial details, such as fairies, are often made of paintable resin.
• Transparent resin: This is the strongest class of resin and therefore the most suitable for a range of 3D-printed products. Often used for models that must be smother to the touch and transparent in appearance.

Transparent resins of clear and colored varieties are used to make figurines, chess pieces, rings and small household accessories and fixtures.

Metal

The second-most-popular material in the industry of 3D printing is metal, which is used through a process known as direct metal laser sintering or DMLS. This technique has already been embraced by manufacturers of air-travel equipment who have used metal 3D printing to speed up and simplify the construction of component parts.

DMLS printers have also caught on with makers of jewelry products, which can be produced much faster and in larger quantities — all without the long hours of painstakingly detailed work — with 3D printing.

Metal can produce a stronger and arguably more diverse array of everyday items. Jewelers have used steel and copper to produce engraved bracelets on 3D printers. One of the main advantages of this process is that the engraving work is handled by the printer. As such, bracelets can be finished by the box-load in just a few mechanically programmed steps that do not involve the hands-on labor that engraving work once required.

The technology for metal-based 3D printing is also opening doors for machine manufacturers to ultimately use DMLS to produce at speeds and volumes that would be impossible with current assembly equipment. Supporters of these developments believe 3D printing would allow machine-makers to produce metal parts with strength superior to conventional parts that consist of refined metals.

In the meantime, the use of 3D parts is taking flight in the aerospace industry. In what has been the most ambitious push of its kind, GE Aviation plans to print engine injectors at an annual rate of 35,000 units by 2020.

The range of metals that are applicable to the DMLS technique is just as diverse as the various 3D printer plastic types:

• Stainless-steel: Ideal for printing out utensils, cookware and other items that could ultimately come into contact with water.
• Bronze: Can be used to make vases and other fixtures.
• Gold: Ideal for printed rings, earrings, bracelets and necklaces.
• Nickel: Suitable for the printing of coins.
• Aluminum: Ideal for thin metal objects.
• Titanium: The preferred choice for strong, solid fixtures.

In the printing process, metal is utilized in dust form. The metal dust is fired to attain its hardness. This allows printers to bypass casting and make direct use of metal dust in the formation of metal parts. Once the printing has completed, these parts can then be electro-polished and released to the market.

Metal dust is most often used to print prototypes of metal instruments, but it has also been used to produce finished, marketable products such as jewelry. Powderized metal has even been used to make medical devices.

When metal dust is used for 3D printing, the process allows for a reduced number of parts in the finished product. For example, 3D printers have produced rocket injectors that consist of just two parts, whereas a similar device welded in the traditional manner will typically consist of more than 100 individual pieces.

Carbon Fiber

Composites such as carbon fiber are used in 3D printers as a top-coat over plastic materials. The purpose is to make the plastic stronger. The combination of carbon fiber over plastic has been used in the 3D printing industry as a fast, convenient alternative to metal. In the future, 3D carbon fiber printing is expected to replace the much slower process of carbon-fiber layup.

With the use of conductive carbomorph, manufacturers can reduce the number of steps required to assemble electromechanical devices.

Graphite and Graphene

Graphene has become a popular choice for 3D printing because of its strength and conductivity. The material is ideal for device parts that need to be flexible, such as touchscreens. Graphene is also used for solar panels and building parts. Proponents of the graphene option claim it is one of the most flexible of 3D-applicable materials.

The use of graphene in printing received its largest boost through a partnership between the 3D Group and Kibaran Resources, an Australian mining company. The pure carbon, which was first discovered in 2004, has proven to be the most electrically conductive material in laboratory tests. Graphene is light yet strong, which makes it the suitable material for a range of products.

Nitinol

As a common material in medical implants, nitinol is valued in the 3D printing world for its super-elasticity. Made from a mixture of nickel and titanium, nitinol can bend to considerable degrees without breaking. Even if folded in half, the material can be restored to its original shape. As such, nitinol is one of the strongest materials with flexible qualities. For the production of medical products, nitinol allows printers to accomplish things that would otherwise be impossible.

Paper

Designs can be printed on paper with 3D technology to achieve a far more realistic prototype than a flat illustration. When a design is presented for approval, the 3D-printed model allows the presenter to convey the essence of the design with greater detail and accuracy. This makes the presentation far more compelling, as it gives a more vivid sense of the engineering realities should the design be taken to fruition.

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Everything you need to know about 3D printing materials

Here is a guide to help you learn about the materials used in modern industrial and home 3D printing.

When it comes to 3D printing, there is (almost) nothing impossible when it comes to materials, and researchers are constantly creating new ones.

There are certain "master" materials. The most common of these are plastics, ranging from industrial grade plastics like PEEK to very easy-to-handle plastics like PLA. Another common material is polymers, which are used in SLA printers. Composites are another category, and, as the name suggests, they are created (as if composed by a composer) by combining several materials, and the best is taken from each. The next large group of materials are metals. They are printed only by industrial machines. nine0005

In this guide, we will only consider commercially available 3D printing materials. This means that we have excluded those that cannot be bought in the store, such as biological ones.

So, it's time to start talking about what materials you can work with in 3D printing, about their applications, properties and technologies.

Which material should I choose?

Sorry, but it depends on a lot of circumstances. For example, if you need to print a food container, you will need a 3D printing material that is also food compatible, like PETG. If you want to see in advance and on a smaller scale what will then be made as a result of injection molding, then it is not necessary to immediately use expensive materials when thermoplastics such as nylon are available. nine0005

There are also additive technologies such as Binder Jetting (jet printing with a binder) or stereolithography, which greatly expanded the range of materials used in 3D printing. Many jobs that have been the domain of manual craftsmen for centuries are now automated and can be done by anyone with even the slightest understanding of 3D printing 3D modeling. Here you can point to the wide possibilities of producing full-color concepts, architectural models and visualization of art projects from paper (SDL), sandstone (Binder Jetting) and polymers (PolyJet). Thus, it can be said that 3D printing materials have led to a kind of democratization of rapid prototyping of design ideas. nine0005

Materials for 3D printing with metals have revealed forms and applications that were previously unimaginable. Nowadays, it is no longer surprising that the aerospace industry is creating complex one-piece structures that use less material than before, and are therefore lighter, resulting in lower fuel consumption for aircraft compared to traditional approaches.

PLASTIC

Most consumer goods today are made from thermoplastics, so this guide to 3D printing materials would be incomplete without them. And if we talk about widespread things, then here the plastics come out in all their glory. Designers and engineers prefer to create functional prototypes from 3D printing materials with the same or very similar properties as injection molding materials, the technology that creates the final product. nine0005

Most 3D printing thermoplastics can be handled at home in much the same way as professional solutions. The only thing is that some experts began to stare at laser sintering instead of filament fusing (FFF).

ABS

(Source: Wikipedia)

Do you remember the quality of Lego bricks? And this is ABS plastic, which is one of the most common materials for desktop 3D printing today.

It is completely inexpensive, strong and light. ABS filament comes in a variety of colors. There are some complaints about the smell that ABS emits when heated to its melting point, and if you're worried about that, there are alternatives like PLA. Because ABS is printed at temperatures between +220 and +250 °C, it is recommended to use a heated platform and in a closed working space so that the material cools in a controlled manner and does not warp. Also, 3D printing materials like ABS break down when exposed to atmospheric moisture, so you need to store them in airtight bags or containers. nine0005

Learn more about ABS: Everything you need to know about ABS filament for 3D printing

• Technologies: FDM, resin inkjet, SLA, PolyJetting
• Features: Rugged, lightweight, high resolution, quite flexible
• Applications: architectural models, concepts, assembly models, mass production

PLA

Another crowd favorite in our guide to 3D printing materials is PLA, which is made from cornstarch (although sugar cane and tapioca are also available). This is a simple material that exudes a pleasant sweetish aroma when heated, which is why many people prefer it over ABS. In addition, it can print disposable tableware and does not shrink as much when cooled compared to ABS. However, PLA is not as durable as ABS, and is afraid of heat. Therefore, ABS is better for any working structures. nine0005

(Source: thingiverse)

Don't Miss: PLA Durability, Biodegradability Experiment

PLA is sold in a variety of colors and is found in many composites that give it the appearance of, for example, wood or metal. Like ABS, PLA filament breaks down when exposed to moisture in the air, so store it in airtight bags or containers.

• Technologies: FDM, SLA, SLS
• Features: easy to print, no toxic smell when printed, food grade
• Applications: concepts, assembly models, functional models, serial production

Nylon (polyamide)

Thanks to its flexibility and strength, nylon has become a leader in a wide range of applications, from engineering to artistic. In some places it is simply called "white plastic". Nylon printouts have a rough surface that can be easily polished. Among FDM filaments, nylon has the strongest layer bonding, making it ideal for 3D printing parts that require high tensile strength and mechanical strength. Like other thermoplastics, nylon decomposes when exposed to ambient moisture and is best stored in airtight containers or bags. nine0005

• Technologies: FDM, SLS
• Characteristics: strong, smooth surface (after polishing), rather flexible, chemically resistant
• Applications: concepts, functional models, medical applications, instruments, visual arts

PEEK

PEEK is another 3D printing material designed for heavy duty parts. Plastics of this family perfectly tolerate mechanical stresses, temperature fluctuations and chemical influences. And that's not it. PEEK parts can be irradiated with X-rays and gamma rays. And with such reliability, this material is easily processed and produced. But here there is an ambush in the temperature, which in a 3D printer should reach +400 ° C, and it is better to entrust such work to professionals. In addition to high cost, security considerations can also be an argument for abandoning it. PEEK materials with their excellent properties are used in the most demanding applications - automotive, aerospace, chemical and medical industries. In particular, medical instruments and semiconductor components can be mentioned. nine0005

• Technologies: FDM, SLS
• Characteristics: biocompatible, very durable, heat resistant, wear resistant
• Applications: series production (automotive, aerospace, chemical and medical industries)

PET

Our next 3D printing material is PET, the material used to make plastic bottles, another alternative to ABS. Unlike ABS, PET does not stink when melted and is strong and flexible without the stench. More importantly, PET does not require heated print bed. The material gives a shiny surface, it is not hazardous to food, and this in some cases makes it a popular choice. Store PET materials for 3D printing in airtight bags or containers, the material is afraid of moisture. nine0005

• Technologies: FDM
• Characteristics: durable, food compatible, flexible, gives a smooth surface
• Applications: assembly models, mass production, functional models

PETG

PETG is a version of PET combined with glycol that has received a number of desirable properties in the 3D printing business, such as high transparency. What's more, PETG materials can be printed at lower temperatures and at higher flow rates (up to 100 mm/s), which speeds up production. PETG objects are not afraid of the weather, so they can often be found in gardens. Another commercial quality is food compatibility. Store PETG in airtight bags or containers, the material is afraid of moisture. nine0005

Don't Miss: All You Need to Know About 3D Printing with PETG Filament

• Technologies: FDM
• Features: Rugged, food grade, all weather, flame retardant
• Applications: concepts, assembly models, functional models, serial production

ULTEM

ULTEM is an amazing 3D printing material often found in demanding applications. On the one hand, the plastics of this family perfectly tolerate mechanical stresses, temperature fluctuations and chemical influences, but at the same time they are easy to process and obtain. The only problem is heat resistance, because the extrusion temperature in a 3D printer must reach +400 ° C, and for safety reasons, it is better not to do this work at home, but to entrust it to specialized 3D printing services. Due to its ruggedness, ULTEM is used in the most demanding applications in the automotive, aerospace, chemical and medical industries. It can be found in electrical circuits, medical instruments, and microchip sockets. nine0005

• Technologies: FDM, SLS
• Characteristics: biocompatible, very durable, heat resistant, wear resistant
• Applications: series production (automotive, aerospace, chemical and medical industries)

HIPS

HIPS has two main applications. First of all, it is often used in FDM or SLA printing as a backing material because it dissolves in a substance called limonene. With similar properties, HIPS works best in combination with ABS. But, if you decipher the name of this plastic, and HIPS is High-Impact Polystyrene, i.e. high-impact polystyrene, it becomes clear why it is also widely used for the manufacture of containers and in general where increased impact resistance is important. When printing, HIPS gives off fumes, so the room must be ventilated, especially at home. Like many other materials for 3D printing, this one is also capricious in relation to environmental conditions, so it must be stored tightly. nine0005

• Technologies: FDM, SLA
• Characteristics: soluble, soft to the touch
• Applications: assembly models, print stands, shipping containers

PVA

PVA, like HIPS, was designed as a soluble support material, but unlike all other similar materials, it dissolves in plain water. And, like most filaments, it needs to be stored in an airtight container.

• Technologies: FDM
• Characteristics: instant
• Applications: assembly models, printing supports

COMPOSITES

Composites are filaments made up of several materials and using the best qualities of each. PLA, for example, can be paired with everything from wood to metal. Other composites are targeted at specific industries or applications and are used, for example, in engineering applications.

Conductive

A relatively new addition to the filament shelf are 3D printable conductive materials that open up many interesting possibilities. Such materials can be used, for example, in touch panels or in MIDI instruments. Other uses for conductive composites are wearable electronics, computer-to-computer interfaces, Arduino boards, and more for DIY projects. Conductive filaments for 3D printing are usually based on PLA or ABS, each with its pros and cons. Conductive ABS is more durable and heat-resistant than PLA-based, but has the same odor issues as regular ABS. nine0005

• Technologies: FDM
• Features: conductive
• Applications: DIY projects

All "metal" filaments on the market are actually thermoplastics mixed with a small amount of metal. Such 3D printing materials allow you to create objects with the visual properties of these metals. Metal-plastic filaments are heavier than conventional thermoplastics. Popular composites for 3D printing are bronze, copper, steel, and iron. Keep in mind that these printouts require post-processing to make them look like metal. Also make sure your printer's nozzle can handle this material. nine0005

• Technologies: FDM
• Features: metal look
• Applications: fine arts

Alumide

This is a nylon variant with aluminum particles. In terms of durability and physical characteristics, it is very similar to nylon. The difference is that it is shiny, wear-resistant and has a porous surface. Objects printed with aluminium can be very precise in size, durable and long lasting. Alumide, like other similar materials for 3D printing, lends itself well to various kinds of post-processing, such as polishing and coating. nine0005

• Technologies: SLS
• Features: Rugged, heat resistant, high resolution
• Applications: DIY projects, functional prototypes, mass production

Wood

Human inquisitiveness knows no bounds, so it was only a matter of time before engineers succeeded in adding wood fibers to plastic filament. Wood 3D prints can be processed like real ones, they can be sawn, sanded and painted. And while this kind of exotic 3D printing material is aesthetically pleasing, it doesn't have the same functional characteristics as the original. For example, you will not be able to make a chair out of it. nine0005

Interestingly, by changing the extrusion temperature, it is possible to change the shades of brown in the wood filament. 3D printing at a lower temperature produces a very light shade, while at a higher temperature it produces a solid dark brown. Therefore, if you decide to imitate growth rings in a printout, play with temperature. Depending on the brand of wood filament, the printing process may be accompanied by the smell of wood. Some manufacturers offer a wide selection of such material - birch, olive, bamboo, willow ...

• Technologies: FDM
• Characteristics: fragile
• Applications: concept models, fine arts

METALS

Our guide to 3D printing materials would be incomplete without metals. Metal 3D printing has gained particular popularity in the aerospace, automotive and medical industries for its ability to create complex designs that do not require additional welding or machining. The disadvantage of these materials is that they require a lot of experience in development and combination. nine0005

In addition, they cannot be printed at home because they require high temperatures and large, specialized printers.

Learn more about metal 3D printing in our comprehensive article Everything you need to know about metal 3D printing

Aluminum

• Technologies: direct metal deposition, binder inkjet printing
• Characteristics: light, strong, heat-resistant, not afraid of corrosion
• Applications: functional models, mass production (automotive and aerospace)

Cobalt Chrome

The next material on the list is used for very serious applications. Chrome-cobalt is sometimes referred to as chromium-cobalt-molybdenum or cobalt-chromium, and sometimes simply as a superalloy. Its main use is in medical applications and in the aerospace industry, where it can be found in turbines and jet engines. It has outstanding strength, heat and corrosion resistance and is suitable for fine work. nine0005

• Technologies: direct metal laser sintering, SLM
• Characteristics: biocompatible, durable, corrosion resistant, heat resistant, wear resistant, low electrical conductivity
• Applications: series production (medical and aerospace)

Copper and Bronze

With rare exceptions, copper and bronze are used in investment casting processes and to a lesser extent in formed bed sintering. Due to their electrical conductivity, they are often used in electrical engineering. They are also very popular as art materials and with artisans. nine0005

• Technologies: investment casting, formed layer sintering, direct metal deposition
• Characteristics: electrical conductivity, wear resistance
• Applications: series production (electrical engineering), fine arts

Inconel

Inconel is a super alloy designed for the most extreme conditions. It consists mainly of nickel and chromium and is extremely heat resistant. Also resistant to extreme pressures, Inconel is indispensable in the production of aircraft black boxes and even rocket engine parts. Even more often, these features are used in solutions for the oil and chemical industries. The material is very strong and difficult to process, so direct laser sintering is preferred to obtain products of the desired shape. nine0005

• Technologies: direct metal laser sintering
• Characteristics: heat resistant, wear resistant
• Applications: petroleum, chemical and aerospace industries

Nickel

Nickel alloys are popular for 3D printing applications. Nickel alloy elements are stronger and more durable than traditional methods such as casting. This, in turn, allows engineers to create thinner parts, leading to more fuel-efficient aircraft, for example. There are many types of alloys that combine the characteristics of nickel and other materials such as monel or inconel. nine0005

• Technologies: formed bed sintering, direct metal deposition
• Features: strong, lightweight
• Applications: series production (automotive and aerospace)

Precious metals (gold, silver, platinum)

Most formed bed sintering firms can work with precious metals such as gold, silver and platinum. Here, in addition to the aesthetic qualities of materials, it is very important not to lose a single crumb of precious powder. Therefore, such parts are more often produced where a more easily controlled investment casting technology is used. Precious metals are used as materials for 3D printing in jewelry, medical solutions and electronics. Depending on the technology used, some of these materials may be used for casting. nine0005

• Technologies: Formed-bed sintering, investment casting, bonded inkjet printing
• Features: high resolution, smooth surface
• Applications: jewelry, dentistry, functional models

Stainless steel

If you're looking for cheaper metal in this guide to 3D printing materials, it's stainless steel. It is also very durable and can be used in many industrial and even artistic applications. Stainless steel alloys containing cobalt or nickel are extremely difficult to break, but have excellent elasticity and good magnetic properties. If you need a different color - please: steel can be coated, for example, with gold. The materials in question are mainly used for industrial purposes. nine0005

• Technologies: direct metal deposition, binder inkjet printing
• Characteristics: high resolution, corrosion resistance, some flexibility, strength
• Applications: tools, function models, mass production

Titanium

Pure titanium powder is often used in 3D printing. This is one of the most versatile materials - it is both durable and lightweight. They work with it using the technology of sintering in the formed layer or inkjet printing with a binder. It is most commonly found in demanding medical solutions, such as custom-made prostheses. Other uses for this material are parts and prototypes for aerospace, automotive and tool manufacturing. In addition to the price, it has another unpleasant feature - its powder explodes easily. Therefore, they print in a vacuum or in argon. nine0005

• Technologies: formed bed sintering, binder inkjet printing, direct metal deposition
• Characteristics: biocompatibility, high resolution, heat resistance, high wear resistance
• Applications: tools, function models, mass production (automotive, aerospace and medical)

CERAMIC

(Source: SONY DSC)

Ceramic is such a popular material for 3D printing in specialized services that custom-made coffee mugs, for example, have become commonplace. And with specialized extruders such as the WASP Clay 2.0, ceramics are also relevant in home 3D printing. nine0005

Clay consists of kaolinite and some other minerals, as well as a certain amount of water, which gives it plasticity. After the ceramic piece is printed, it is cured in an oven. The water evaporates and the minerals fuse together, maintaining the object's shape and strength. To make the printout shine, it is covered with glaze and placed in the oven again.

Ceramics can be printed using conventional FDM technology, as well as complex methods such as SLA. Beginning "potters" are offered a choice: glass, porcelain or carborundum (silicon carbide). The resulting products are distinguished by heat resistance and wear resistance and today most often act as works of art, as well as dishes and dentures. nine0005

• Technologies: FDM, binder inkjet, SLA
• Characteristics: heat resistance, wear resistance, brittleness, porous surface
• Applications: fine arts, serial production (dishes, dentistry)

WAX

Wax 3D prints are not usually the final product, but they are an important step in a long journey. They are relevant for very high resolution molding (0. 025 mm), as well as for investment casting. They are often used in the creation of custom-made jewelry, and at a relatively low price. Another industry that uses this kind of 3D printing materials is dentistry. When creating complex structures, wax, due to its low melting point, is an excellent material for props. nine0005

• Technologies: SLA, PolyJet
• Features: high resolution, smooth surface
• Applications: series production (jewelry, dentistry)

PAPER

With selective deposition lamination (SDL) technology, good old stationery around the corner finds its niche in 3D printing. SDL objects are tree-like, full-color, and this makes them popular in architectural and other conceptual models. On the other hand, parts made from SDL are not as strong as those made from other materials and do not have the level of detail that those made from PolyJet plastic or plaster. nine0005

• Technologies: Selective Deposition Lamination
• Features: Cost effective, Recyclable, Full color
• Applications: concept models, fine arts

SANDSTONE

Sandstone as a printing material is sometimes referred to as gypsum (in fact, gypsum is a component of natural sandstone) and is used to create impressive full-color objects in one process. To enhance the color and add strength, the printouts are covered with a protective layer of epoxy, without this the moisture will do its job and the sandstone will discolour. Objects turn out to be fragile, like porcelain, and this must be taken into account at the design stage. Bearing in mind the capriciousness of sandstone, it is mainly used in architectural models, concept prototypes and art projects. nine0005

• Technologies: FDM, binder inkjet, formed bed sintering
• Features: fragile, full color
• Applications: concept models, fine arts

(PHOTO)POLYMERS

(Photo: Nervous System)

Photopolymers are a type of liquid resin that hardens when exposed to ultraviolet (UV) electromagnetic radiation or visible light. Today, they work mainly on two technologies - SLA (stereolithography) and PolyJet. SLA uses a UV laser to project a slice of an object onto the surface of a photopolymer poured into a bath, which solidifies into the shape of the object's layer. This is repeated for all layers. nine0083 PolyJet technology takes a different approach. The printer directs a jet of resin onto a substrate, on which the resin is continuously cured by a UV lamp. SLA prints layers no thinner than 0.1 mm, and PolyJet produces up to 16 microns. And although the methods are similar and they use similar materials, the big difference lies in the methods of working with materials.

All photopolymers are sensitive to sunlight.

SLA Resins

Many SLA Resins are designed to mimic the different properties of the "traditional" materials discussed above. For example, there are materials that are compatible with wax, they are used to create impressions in investment casting. And if biocompatibility is important, then there are thermoplastics for SLA, which are very similar to PLA. Other SLA plastics can be as strong as ABS. There are even composite materials for SLA printing that have the properties of ceramics: the objects obtained on the printer can be put in an oven and then treated like ceramic. nine0005

Resins are an excellent choice for functional and conceptual models. They are especially good if you want to get a large object in a short time, while with a high level of detail. Some polymers even become hard enough for machining after quenching. In addition, high-temperature polymers are a cost-effective replacement for mold materials for low-volume moldings.

The popularity of the SLA process lies in its excellent speed and accuracy. The downside is that polymers are still significantly more expensive than everything that was mentioned here. nine0005

SLA printers are sold, you can work with them both at home and in a small office and use very interesting materials for semi-professional 3D printing.

• Technologies: SLA
• Characteristics: smooth surface, some flexibility
• Applications: concept models, functional models, fine arts, tools (prototypes)

PolyJet resins

(Source: Printshow)

Like SLA resins, PolyJet materials mimic the different properties of "traditional" 3D printing materials. Most PolyJet resins have fairly descriptive names. For example, rigur is designed for strength and sounds similar to the Latin root for hardness. It is also called "simulated propylene" for the similarity of the surface and functionality. A number of 3D printing materials are referred to as "digital ABS" because they are heat resistant and durable. Rubber-like materials are designed for non-slip surfaces and to absorb vibrations. Since there are so many PolyJet polymers, we decided to refrain from a detailed description of each of them. nine0005

It should be noted, however, that PolyJet polymers differ from SLA in that they allow obtaining the so-called. digital materials. These are mixtures of up to three 3D printing materials to obtain specific properties (strength, heat resistance, transparency, etc.) for a specific part and in a specific color range. This is a bright path to radiant prospects. While other materials described in this review allow you to create only a visual imitation of "traditional" objects, objects from PolyJet can also imitate tactile sensations, actually replacing reality. nine0005

PolyJet Resins are an excellent choice for color prototypes of consumer products to test these products with different target audiences. Depending on the chosen material and the final goal, functional models can also be created to evaluate the original. In addition, PolyJet resins are the only 3D printing materials that can simulate multilayer casting. Some PolyJet resins are suitable for actual molding, others are used in high precision parts and have excellent performance for visual prototypes, models and simulations. nine0005

• Technology: PolyJet
• Features: high resolution, smooth surface, flexibility, temperature resistance, transparency
• Applications: concept models, fine arts, jewelry, medical production, instruments (prototypes)

_{Source: 2019 3D Printing Materials Guide - All You Need to Know}

types, applications and properties

3D printing enables rapid and cost-effective prototyping and production of models for a wide range of applications. But choosing the right 3D printing technology is only one side of the coin. Ultimately, the ability to create models with the required mechanical properties, functional characteristics or appearance will depend on the materials. nine0005

This comprehensive guide provides information on the most popular plastic and metal 3D printing materials available, compares their properties and applications, and provides guidance on how to select the most suitable material for your project.

Interactive material

Need help choosing your 3D printing material? Our new interactive materials wizard will help you select the right material from our growing range of polymers, based on your intended application and the properties that matter most to you. nine0005

Get material recommendations

Dozens of plastic materials are available for 3D printing. Each of them has unique properties suitable for specific applications. To make it easier to find the best material for a particular model or product, let's first look at the main types of plastics and the various 3D printing processes.

There are two main types of plastics:

• Thermoplastics is the most common type of plastic. The main feature that distinguishes them from thermosetting plastics is their ability to withstand multiple melting and solidification cycles. Thermoplastics can be heated and shaped into desired shapes. This process is reversible because no chemical bond is formed. As a result, they can be recycled or melted down and reused. Thermoplastics can be compared to butter: it melts and hardens many times. With each melting cycle, the properties of thermoplastics change slightly. nine0005

• thermoset plastics (also called thermosets) remain permanently solid after polymerization. The polymers in thermosetting plastics are crosslinked during the polymerization process, which is induced by heat, light, or appropriate radiation. Thermoset plastics decompose when heated, rather than melt. In addition, they do not change their shape when cooled. It is not possible to recycle thermosetting plastics or restore the material to its original state. Thermosetting is like pie dough: once baked, the pie cannot be melted back into dough. nine0005

The three most common plastic 3D printing processes today are:

• Fused Deposition Modeling (FDM) 3D printers melt and extrude thermoplastic filaments, which the printer nozzle deposits layer by layer on the work area.

• The Stereolithography (SLA) 3D Printer uses a laser to photopolymerize thermoset liquid polymers into a hardened plastic. nine0005

• The Selective Laser Sintering (SLS) 3D Printer is equipped with a high power laser to sinter fine particles of thermoplastic powder.

How-To Video

Can't find the 3D printing technology that best suits your needs? In this video tutorial, we compare Fused Deposition Modeling (FDM), Stereolithography (SLA), and Selective Laser Sintering (SLS) technologies in terms of the top factors to consider when purchasing. nine0005

Watch video

Fused fusion modeling (FDM), also known as fused filament manufacturing (FFF), is the most common form of consumer grade 3D printing, fueled by the proliferation of hobbyist 3D printers.

This method is well suited for making basic experimental models, as well as for quickly and inexpensively prototyping simple products, such as parts that are usually machined. nine0005

Consumer-grade FDM has the lowest resolution and accuracy of any plastic 3D printing process, making it unsuitable for printing complex designs or models with intricate features. It is possible to improve the surface quality of models printed using this technology using chemical and mechanical polishing processes. FDM-based industrial 3D printers, which offer a wider range of engineering thermoplastics, can solve these problems, but are also much more expensive. nine0005

Each layer is formed with a thermoplastic thread. Sometimes, if the layers are not completely adjacent to each other, there may be voids between them. As a result, anisotropic models are obtained, which is important to consider when designing products that must withstand load and be resistant to tension.

FDM 3D printing materials are available in a variety of colors. There are also various experimental mixtures of thermoplastic threads designed to create models with a surface that mimics wood or metal. nine0005

The most common materials for 3D printing in FDM technology are ABS (acrylonitrile butadiene styrene), PLA (polylactic acid) and various mixtures of these polymers. More advanced FDM printers can also print on other materials with different properties, such as increased temperature and chemical resistance, impact resistance, and rigidity.

Material	Features	Material for supporting structures
Shock -resistant polystyrene	Material for the creation of soluble supporting structures, most frequently used with ABS , is dissolved in Limonena of the fiber. Material for supporting structures
Kevlar, fiber optic)	Strong, tough and incredibly hard Only compatible with some expensive industrial 3D printers based on FDM technology	Functional prototypes Clamping fixtures, fixtures, tooling

Invented in the 1980s, stereolithography is the world's first 3D printing technology and is still one of the most popular among professionals today.

3D printed models have the highest resolution and accuracy, the sharpest detail and the smoothest surface of any other plastic 3D printing technology. Resin 3D printing is a great option for producing highly detailed prototypes that require tight tolerances and smooth surfaces such as molds, templates, and functional models. Models printed using SLA technology can be easily polished and/or painted after printing, resulting in highly detailed finished products. nine0005

Models printed on 3D printers using SLA technology are generally isotropic: their strength is more or less constant and independent of orientation, since chemical bonds occur between each layer. This results in models with predictable mechanical characteristics critical for applications such as fasteners, fixtures, finished products, and functional prototypes.

Stereolithography supports a wide range of plastic 3D printing materials. nine0005

SLA 3D printing is versatile and provides a wide range of optical, mechanical and thermal properties that match those of standard, engineering and industrial thermoplastics.

Sample

Experience Formlabs print quality for yourself. We will send a free print sample directly to your office. nine0005

Request a free sample

Selective laser sintering (SLS) 3D printing is a technology trusted by engineers and manufacturers across industries to create durable and functional models. With its low model cost, high performance, and use of common materials, this technology is well suited for a wide range of applications, from rapid prototyping to low-volume production, limited trial runs, or custom-made products. nine0005

The green powder supports the model during printing and eliminates the need for special support structures. As a result, SLS is ideal for complex geometries, including internal features, undercuts, thin walls, and negative draft features.

Like stereolithography, SLS produces more isotropic models than FDM models. Models created with SLS technology have a slightly rough surface due to powder particles, but have almost no visible layer lines. nine0005

SLS 3D printing materials are ideal for a range of functional applications, from consumer product design to manufacturing and healthcare applications.

Compared to FDM and SLA technologies, SLS technology allows the use of a limited number of materials. However, the available materials have excellent mechanical properties. They have strength comparable to die-cast models. The most common selective laser sintering material is nylon, a popular engineering thermoplastic with excellent mechanical properties. Nylon is light, strong and flexible, resistant to impact, heat, chemicals, UV radiation, water and dirt. nine0546 Functional prototypes
Products for the final use of
Medical devices TPU Flexible, elastic, elastic
resistant to deformation
High resistance
Excellent damping ability 9054 end use
Medical devices Nylon composites Nylon materials reinforced with glass, aluminum or fiberglass for greater strength and rigidity Functional Prototypes
End-Use Structural Products

Sample

Experience Formlabs SLS print quality for yourself. We will send a free print sample directly to your office.

Request a free sample

Different 3D printing materials and processes have their own advantages and disadvantages that make them suitable for different scenarios. The following table provides a brief overview of some of the main features and factors to consider. nine0546 Disadvantages Poor accuracy
Poor detail
Limited fit to design design
High cost of industrial devices if precision and high performance materials are required Susceptibility to prolonged UV exposure More expensive material choice69 Applications Low Cost Rapid Prototyping
Basic experimental models
Production of special end-use products using professional industrial devices and materials Functional prototypes
Templates, molds and tooling
Dental products
Prototypes and molds for casting jewelry
Props and models Functional prototypes
Small-scale production, production of limited trial runs, creation of products to order Materials Standard thermoplastics such as ABS, PLA and their various blends on consumer grade devices. High performance composites on high value industrial applications Various polymers (thermosetting plastics). Standard, engineering (similar to ABS and PP, flexible, heat resistant), molding, dental and medical (biocompatible). Engineering thermoplastics. Nylon 11 Powder, Nylon 12 Powder and their composite materials, thermoplastic elastomers such as TPU. nine0546

There are several 3D printing processes not only from plastics, but also from metals.

Metal FDM printers are similar in design to traditional FDM printers, but use extruded metal rods held in place by a resin binder. The finished models are in an intermediate state and then sintered in an oven to remove the binder.

SLM and DMLS printers are similar to SLS printers, but instead of polymer powders, they fuse metal powder particles layer by layer using a laser. 3D printers based on SLM and DMLS technologies can create strong, precise and complex metal products, making this process ideal for the aerospace, automotive and medical industries.

• Titanium is a light metal with excellent mechanical properties. It is strong, hard and highly resistant to heat, oxidation and acids. nine0005

• stainless steel has high strength, ductility and corrosion resistance.

• Aluminum is a lightweight, durable, strong metal with good thermal properties.

• Tool Steel is a hard, scratch-resistant material that can be used to print end-use tools and other high-strength products. nine0005

• nickel alloys have high tensile strength, creep and tensile strength, as well as heat and corrosion resistance.

Compared to plastic 3D printing technologies, metal 3D printing is much more expensive and difficult, and therefore beyond the reach of most companies.

As an alternative to casting workflows that produce metal models cheaper and faster than traditional methods and provide greater design freedom, SLA 3D printing is well suited. nine0005

Another alternative is galvanization of SLA printed models. It involves applying a layer of metal to plastic using electrolysis. This combines some of the best qualities of metal (strength, electrical conductivity, corrosion and abrasion resistance) with the special properties of the base (usually plastic) material.

Plastic 3D printing is well suited for creating templates that can be molded to produce metal models. nine0005

With so many materials and options available for 3D printing, making the right choice can be difficult.

We offer a 3-step process for selecting the right material for 3D printing.

Plastics used for 3D printing have different chemical, optical, mechanical and thermal characteristics that affect the properties of 3D printed models. As you move from the intended use case to the actual operating environment, the performance requirements increase accordingly. nine0005

Requirement	Description	Recommendations
Low efficiency	Example: Prototype mold for a ladle for ergonomic testing. Other than surface quality, there are no performance requirements. nine0005	FDM PLA SLA: Standard Resins, Clear Resin (transparency), Draft Resin (fast)
Medium Efficiency	For validation or pre-production use, printed models should have properties as close as possible to those of final production models , for functional testing, but do not meet stringent requirements regarding service life. Example: housing for electronic components to protect against sudden impacts. Functional characteristics include the ability to absorb impact energy. In addition, the body must snap into place and retain its shape. nine0005	FDM ABS SLA: Engineering Resins SLS: Nylon 11 Powder, Nylon 12 Powder, TPU
High Efficiency	Final 3D printed models need to be highly stable to achieve end use products to wear and tear over a certain period of time, whether it be a day, a week or several years. Example: shoe soles. Functional features include rigorous cycling and unloading life testing, color fastness over many years, and tear resistance, among other things. nine0005	FDM Composites SLA: Engineering, Medical, Dental or Jewelry Resins SLS: Nylon 11 Powder, Nylon 12 Powder, TPU, Nylon Composites

material requirements: material properties that will satisfy these requirements. These indicators are usually given in the technical specifications of the material. nine0005

Requirement	Description	Recommendations
Tensile strength	Resistance to fracture under tension. High tensile strength is important for structural, load-bearing, mechanical or static models.	FDM PLA SLA: Clear Resin, Rigid Resin SLS: Nylon 12 Powder, Nylon Composites
Flex Modulus	Material resistance to bending under load. Indicates either rigidity (high value) or flexibility (low value) of the material.	FDM PLA (High), ABS (Medium) SLA: Rigid Resin (High), Tough Resin and Durable Resin (Medium), Flexible Resin and Elastic Resin (Low) SLS: Nylon composite materials (high value), Nylon 12 Powder (medium value)
Elongation	Material resistance to tensile failure. Allows you to compare the degree of stretching of flexible materials. It also indicates whether the material is stretched or immediately destroyed. nine0546	FDM ABS (medium), TPU (high) SLA: Tough Resin and Durable Resin (medium), Flexible Resin and Elastic Resin (high) SLS: Nylon 12 Powder (medium), Nylon 11 Powder (medium), TPU (high)
Impact strength	The ability of a material to absorb impact and its energy without breaking. Shows toughness and durability. Allows you to determine how easily the material breaks when it falls to the ground or collides with another object. nine0546	FDM ABS, Nylon SLA: Tough 2000 Resin, Tough 1500 Resin, Gray Pro Resin, Durable Resin SLS: Nylon 12 Powder, Nylon 11 Powder a certain load. Indicates whether the material is suitable for high temperature applications.	SLA: High Temp Resin, Rigid Resin SLS: Nylon 12 Powder, Nylon composites
Hardness (durometer)	Material resistance to surface deformation. Allows you to determine the right degree of plasticity for soft plastics such as rubber and elastomers for a particular application.	FDM TPU SLA: Flexible Resin, Elastic Resin SLS: TPU
Tear resistance	Material resistance to notching under tension. This indicator is important for evaluating the durability and wear resistance of soft plastics and flexible materials such as rubber. nine0546	FDM TPU SLA: Flexible Resin, Elastic Resin, Durable Resin SLS: Nylon 11 Powder, TPU
Creep	Creep is the tendency of a material to permanently deform under the influence of constant stress: tension or bending, compression, shear . Low creep indicates durability of hard plastics and is very important for structural models.	FDM ABS SLA: Rigid Resin SLS: Nylon 12 Powder, Nylon 9 composites0546
Compression set	Irreversible deformation after material compression. An important indicator for soft plastics and applications where elasticity is needed. Indicates whether the material will restore its original shape after the load is removed.	FDM TPU SLA: Flexible Resin, Elastic Resin SLS: TPU

For more information on material properties, see our guide to the most common mechanical and thermal properties. nine0005

By converting performance characteristics into material requirements, you can most likely find out which material, or small group of materials, is right for your application.

If several materials meet your basic requirements, a broader range of desired characteristics, as well as the advantages and disadvantages of these materials and processes, can be considered for the final selection.

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