3D printed solutions


3D Printing Solutions by Arkema

A market leading product portfolio

Liquid

resins

Radiation curing

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Thermoplastic

powders

Power bed fusion

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Thermoplastic

pellets

Filament extrusion

3D printing filament extrusion

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A better use of material properties

We provide support to choose the right material and the right printing technology based on your applications. We offer high-performance materials for 3D printing for highly demanding applications. Check our materials for chemical resistance, transparency, impact resistance, dielectric properties, heat resistance or energy return applications.

Chemical resistance - Kepstan

® PEKK​ In this video, we tested the reaction of Kepstan® PEKK and PEI to MEK. After 8 hours of exposure to MEK, we observe how PEI printed piece has changed in color, while PEKK remains the same. High-Performance Materials for FFF 3D printed Kepstan® PEKK withstands aggressive chemicals and suits extreme applications.

High Toughness and Impact resistance - N3xtDimension

® liquid resin UV/LED liquid resins are the top choice if you are looking to achieve tough, transparent and highly detailed parts.

Impact resistance - Rilsan

® PA11​ In this video, we tested SLS printed Rilsan® PA11​ with PA12 for impact resistance. Using the vertically installed tube and falling steel ball test, we can see that the PA12 piece has broken while PA11​ withstand the impact with the steel ball and the piece remains intact. SLS printed Rilsan® PA11 shows superior impact resistance event -30 °C low temperatures.

Dielectric resin ​- N3xtDimension

® liquid resin Our N3xtDimension® UV/LED liquid resins with dielectric properties are the material of choice for radio frequency technology applications.

Ductility – Rilsan

® PA11​ In this video, we compared 3D-printed pieces of PA11 and PA12 for ductility. After repetitive manipulations like folding and unfolding, we see how the PA11 piece remains tough and flexible without breaking. Use Rilsan ® PA11​ powder when you need ductility, rigidity and strength for your 3D printing application. 

Heat resistance​ - N3xtDimension

® liquid resin N3xtDimension® heat resistant UV/LED curing resins can resist up to 150°C without compromising on mechanical properties.

Energy return – Pebax

® TPE ​ Pebax® TPE ​is an energetic elastomer that is perfect for applications requiring lightweight, flexibility and energy return. High energy return means a high percentage of the energy put into flexing the polymer (i.e. the step of an athlete) is returned during rebound. Compared to TPU polymers, Pebax® elastomers exhibit much lower energy loss, even at very low temperatures.

Save time during design phase

The ability to reliably simulate part behavior is key in predicting an optimal design and making the most of 3D printing. We can recommend to our customers the best trade off between cost and properties for each part, and are dedicated to being at the forefront of simulation tools.                                                               

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Collaborative development

We partner with our customers to develop custom materials and resins for their unique end-use applications. With our dedicated team of scientists and our three global centers of excellence, for each of the printing technologies, we have enabled the success for our customers in numerous markets. 

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Global capability, local expertise

We are ready to support our partners globally. Our teams are actively investing in all three regions – Europe, Asia, and North America – to serve you better. Our worldwide presence enables us to provide quick, local expertise from customized solution design to implementation

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White paper: Expanding Industrial Applications of Additive Manufacturing with Advanced Material Solutions 
  • Why additive manufacturing is revolutionary for industries? 
  • What are the highest performing materials for additive manufacturing in industrial application?
  • How to democratize additive manufacturing? 

The high-performance materials for 3D printing are evolving in tandem with advancement of additive-manufacturing technology.  The material research and development in additive manufacturing is rooted in the understanding of the past practices and bridging the gap between traditional and emerging technologies.

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Case study - 3D printing 
 

3D printed and tailor-made: orthopedic insoles made with advanced bio-circular polyamide 11

 

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Our specific offering for other industries:

3D Printing Solutions - ALSO Holding AG

The solution in a nutshell: 3D printing is being used in many different business areas to create interactive, mechanical and technical solutions. Read about some of them below.

3D Solutions by business segment

3D Solutions by workflow

Overview of 3D Printing Solutions

With our market leading vendors we develop 3D Printing and additive manufacturing solutions for customers in various business segments.

Benefit from expert knowhow

Professional solutions for Additive manufacturing (3D Printing) requires five steps:

  • Production of 3D Data
  • Preparation of 3D Data
  • Manufacturing / Printing of 3D Data
  • Post Processing to get a final Object
  • Automation and Quality Control

and a good knowledge of traditional manufacturing (processes) and materials.

Solution Power

Identification of the right 3D solution for the customer, by…
Support with the ROI assessment before the implementation of a new workflow.
Help in determining the appropriate tools and resources for creating models for 3D printing.
Optimize and finalize the process with post processing procedures and products.


3D Printing in education offers you wide range of new additional options - you can print a 3D brain, a planet, or anything you want to capture the attention of your class and help them learn

3D printing is being used in many schools to create interactive, mechanical and technical lessons. This inspires young minds and makes learning more fun. Due to 3D printing versatility in school subjects, a 3D printer can be used in any school subject. Here are a few examples:


As soon as they see it, they’ll be captivated. Young minds love the latest technology, and it’s the perfect way to help them learn together and enjoy the process. 3D printing Inspires students with hands-on learning about science, engineering, business, design and technology or whatever you choose to print.

Let us help you on your 3D printing journey, offer you the advice schools require to justify the change from learning, not just from traditional auditory methods, but also visual and kinaesthetic methods with the power of 3D printing.


3D printing sounds like something from science fiction, however its been around for about 30 years.

A 3D printer works by “printing” objects–but instead of using ink uses granular materials to build up the image in layers. The benefits of this is that students can learn though visual and kinaesthetic learning styles.

That’s up to 70% of students default way to learn, compared to the traditional auditory learning style, which is only 30% of students preferred learning style.


There are several reasons why additive manufacturing works perfectly for medical applications. An on-demand 3D printing service can be used to quickly manufacture medical devices for patients in need.

Complexity

Surgical implants require complex and organic structures to be accepted by the host tissue. These structures are prohibitively expensive with traditional manufacturing methods, but a 3D printer can create them with no additional cost.

Sterilization

Medical devices must be made from sterilizable materials. Most of the materials used for FDM printing or 3D metal printing can be sterilized by steam autoclave or gamma radiation.

Customization

3D printed parts can be shaped to fit perfectly with a patient's anatomy. Dental implants, cosmetic prosthetics, and even scale models can all be created to exact specifications.

Speed

Medical procedures seldom happen on a relaxed schedule. On-demand 3D manufacturing lets hospitals source necessary parts that can be completed with an acceptably short lead time.

Additive manufacturing has been used to produce hearing aids, replacement limbs, surgical implants, and detailed models of organs, bones, and blood cells. Access to this technology has greatly advanced the potentials of the medical field.

Prosthetics

Additive manufacturing has completely revolutionized the prosthetics industry. From cosmetic prosthetics to fully-functional replacement limbs, these devices can be customized to each individual and produced for a fraction of the previous cost.

Surgical guides

Both dental and medical surgeries require extreme precision. A 3D printed guide can help a surgeon line up holes and incisions with a patient's anatomy. Thanks to additive manufacturing, these guides can be produced quickly and to exact specifications.

Implants Models

3D printing can be used to create perfect scale models of patient-specific anatomy and structures. This allows doctors and nurses to study a subject from multiple angles and hopefully find a solution to the medical problem. Additive manufacturing is an affordable way to produce anatomical models; both medical students and experienced professionals take advantage of this technology.


Toys

Production 3D Printing offers a low-cost-of-entry and flexible alternative to injection molding when creating new toys. Allowing designers and businesses to more readily break into the global toy market and scale up. Toys are one of the largest markets for final plastic products in the world.


Toy designers can use 3D printing to create functional models to test and validate among potential users and distributors. This helps to determine the requirements for the final product.

3D printing reduces prototyping time, as it doesn’t require moulds for multiple design iterations. 3D printed prototype toys can be tested for functionality and safety, and the necessary design improvements can be quickly and easily incorporated into the final product design. This way, 3D printing significantly speeds up time-to-market for new toys.


Sports

With the development of advanced Additive Manufacturing materials, the sports industry can enjoy new opportunities for more functional equipment.

Lightweight and durability are two key standards for sports equipment manufacturing. But other than these properties, 3D manufactured sports goods can also enjoy the superior design potential of 3D printing. With lattice structure designs, high-performance sports equipment can be achieved with a much lighter weight than with other manufacturing technique. Along with weight, design for Additive Manufacturing allows to enhance the properties of these high-performance materials, hence to make the most of 3D printed helmets, shinguards, soles, shoes, and much more.


Prototypes

Before launching a new product into the market, a number of steps are required to transform a concept or idea into the final, physical product. Prototyping is a vital stage in this process, giving designers important insights as to how a toy will look and function


To this end, 3D printing is the ideal prototyping method for creating functional, visual prototypes rapidly and cost-effectively.Importantly, 3D printing enables designers to produce multiple prototypes in a very short time – meaning that extensive feedback can be used to formulate the final requirements. The iterative potential of 3D printing therefore enables greater experimentation, leading to greater product innovation, and ultimately better parts.


Spare Parts

Creating spare parts and rethinking the supply chain


As you may know, additive manufacturing is the best technique to manufacture spare parts. While using 3D printing, manufacturing spare parts becomes useful for many different aspects and is starting to be used in some interesting sectors.

3D printed spare parts can be used to repair broken parts that are no longer produced. The automotive sector is making the most of this technology, some big manufacturers are already using it such as Porsche or Jaguar for their classic cars: this is an opportunity for them to recreate theses old parts identically. This technique is also a great advantage for spare parts as it is adapted to the production of small volumes.

Create 3D data by either an CAD Software, 3D Scanning or downloading 3D models from a web database.

Prepare the 3D model to fix errors, adjust the model for 3D printing or optimize the structure - lightweight construction.

3D Printing with the right technology, the right material and the right parameters.

Post Processing of the 3d object by cleaning, surface finishing or coloring the object to a final product.

Automate 3D printed parts are automatically checked, sorted and packaged for the customer.

More about 3D Pre Processing

More about 3D Post Processing

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Problems, defects, 3D printing errors and solutions

Often during the operation of a 3D printer, problems may arise due to which defects appear on the finished model. Or instead of a neat product, plastic noodles suddenly appear on the table.

In fact, the causes of defects can be conditionally divided into 2 types - these are physical and software.

Physical ones are those that arise due to problems with the mechanics or any other causes that can be eliminated physically. These include problems with printer mechanisms (belt tension, backlash), clogged or deformed nozzle, incorrect table geometry, etc. nine0003

Software - these are defects that occur due to incorrect slicer settings or, less often, errors in the printer firmware. For example, incorrectly selected print speed, retract settings, incorrectly selected temperature for plastic, etc.

Very rarely, the problem may lie in the wrong or “flying” printer firmware (although usually the printer simply will not start then), overheating of some boards during printing, etc. These are rather special cases, so we will not consider them. nine0003

Model peels off or does not stick to the build plate

This is the most common 3D printing problem. Every 3D printer has had a case when the first layer treacherously rolls, clinging to the extruder, or the most offensive - when it tears off a partially printed model from the table. The first layer must stick tightly otherwise nothing will be printed.


Gap between table and nozzle 9 too large0023

This is the most common reason. You just need to set the correct gap between the table and the nozzle.

Modern printers often use an auto-calibration (auto-leveling) table system or an auxiliary table leveling program. To calibrate such printers, use the instructions. If there is no manual, it can be downloaded from the manufacturer's website.

If you have a simple printer without auto-calibration, a self-assembly or KIT kit, use a probe or a piece of paper folded in half to calibrate. The probe should be slightly pressed against the table by the nozzle. Before calibration, the table and extruder must be heated. Align the table surface over each adjustment screw (there may be 3 or 4) in turn, and only then check the center point. nine0003

If you're having trouble getting your table surface perfectly level, try raft printing. Raft is a thick substrate in several layers that is printed under the model. It will help smooth out the slight curvature of the table.


A small cheat sheet to determine the correct gap on the first layer

Plastic with poor adhesion

Some types of plastic, due to various reasons, such as large shrinkage, do not adhere well to the surface of the printing platform. In this case, try using stickers or special 3D adhesives to improve adhesion between the table and the first layer of plastic. nine0003

In the early days of 3D printing, there were experiments with different homemade 3D adhesive recipes. ABS diluted in acetone, BF glue, sugar syrup and even beer. Some experiments have been successful. Until now, some enthusiasts use some types of hairspray or glue sticks as 3D glue. But still they are inferior in their properties to industrial 3D adhesives.

Some types of high temperature plastics with a high percentage of shrinkage (ABS, Nylon, etc.) may peel off the table during printing. This is due to uneven cooling and “compression” of the model (the lower layers have already cooled down, but the upper ones have not yet). For such plastics, it is imperative to use a 3D printer with a heated table and a closed case. nine0003

Plastic temperature too low

The hotter the plastic is when it exits the nozzle, the better it will adhere to the print platform. It is better to print the first 5-10 layers at a higher temperature (+ 5-10 degrees) and turn off the blower fan.

Wrong first layer settings (speed and thickness)

A thicker layer sticks easier, so the standard first layer is 0.3mm thick. With an increase in print speed, the heating block may simply not have time to heat the plastic to the desired temperature and it will stick to the table worse. Before printing, check the speed and thickness settings of the first layer in the slicer. nine0003

A lot depends on how the 3D printer prints the first layer. Try to control the printing of the first layer and only then leave the printer to work alone.

Plastic does not choke from nozzle

The printer has already begun to print, but the print table remains empty. Or part of the model did not print.


Clogged nozzle

In 3D printing, a nozzle is a consumable. The nozzles are clogged or worn out (frequency depends on the type of plastic). The simplest thing is to replace the nozzle. But if there was no spare at hand, you can try to clean the old one. To do this, there is a whole set of thin needles. Or you can heat a clogged nozzle above the melting point of the plastic and “burn out” the blockage. But later it is still better to replace the nozzle. nine0003

Low temperature nozzle

You need to increase the temperature of the extruder in the slicer settings or check the thermistor and heating block. Sometimes the thermistor may not read the temperature correctly due to a malfunction or incorrect 3D printer firmware settings.

If the problem occurs after replacing the thermistor - contact the manufacturer or read articles about PID tuning.

Empty extruder

As the extruder heats up, plastic begins to ooze out of the nozzle. Because of this, the extruder may start printing half empty. Because of this, part of the first layer is not printed. You can push the plastic manually by simply pushing the bar into the nozzle. Or solve this problem programmatically - in the slicer, add a contour print around the model (one line).

Some manufacturers and 3D enthusiasts add a line print on the edge of the table at the beginning of each GCode. This is done so that there is plastic in the nozzle by the time the model is printed. nine0003

Feed mechanism does not push through plastic

The plastic pushes the feed mechanism to the extruder - a motor with a special pulley put on the shaft. If for some reason the plastic is not pushed through (nozzle clogged, extruder temperature low, etc.), then the pulley “gnaws” through the bar. You need to push the plastic bar with your hands or cut off the damaged piece.


Elephant foot

The first layers of the model are wider and protrude beyond the boundaries of the model. This is due to the fact that the upper layers put pressure on the first ones that have not yet cooled down and flatten them. nine0003


High table temperature

Due to the too high temperature of the table, the lower layers remain soft for a long time. Try lowering the table temperature. It is better to reduce gradually (in increments of 5 degrees). You can try to turn on the blower when printing the first layers.

Small gap between nozzle and platen

If, when printing the first layer, the nozzle is too close to the table, then excess plastic will be forced out. After a few coats, this will not be as noticeable, but can lead to the effect of an “elephant's foot”. nine0003

Plastic re-extrusion

When too much material is squeezed out of the nozzle, the walls of the model are not smooth, but bumpy, with sagging.


The solution is software - in the settings of the slicer, you need to set the material feed rate (fluidity) to a lower value. The average value is 95-98%.

It is worth checking the diameter of the rod. If its size is greater than 1.75, then the plastic will be squeezed out more than necessary. nine0003

Plastic underextrusion

The plastic is squeezed out too little, because of this, gaps may appear between the layer. The finished model will be fragile and fragile.


Wrong thread diameter

Check the filament diameter in the slicer settings. Sometimes, instead of the popular 1.75, the default is 2.85.

Incorrect feed factor settings nine0003

Check the fluidity settings in the slicer. The average should be 95-98%.

Clogged nozzle

Something could get into the nozzle and partially block the exit of the plastic. Visually, the plastic will choke from the nozzle, but in a smaller amount than necessary for printing.



Hairiness or cobwebs on finished model

Thin threads of plastic protrude from the outer wall of the model (most often on one side). The defect appears due to the flow of plastic from the nozzle during idle movement. nine0003


Insufficient retract

A retract is a slight pull of a plastic filament from an extruder. Due to the retract when the extruder is idle (from layer to layer or from model to model), heated plastic does not drip from the nozzle. For some flowable plastics (eg PETG) the speed and amount of retraction must be increased.

"Hairiness" can be easily removed by grinding or cutting off the threads with a sharp scalpel. nine0003

High temperature extruder

The higher the extruder temperature, the more liquid the plastic becomes. It is important to find a balance so that the plastic is not too liquid and sticks well in layers.

In the selection of the optimal extruder temperature, a test model - a tower - helps a lot. It clearly shows how plastic behaves when printed at different temperatures.

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Temperature test nine0003

Top "perforated" or uneven

The top of the model is bumpy or with holes. The problem may arise if the top of the model is flat. For example, like a cube.


Insufficient airflow

When printing the top plane (cover), the plastic does not have time to cool down and remains too liquid. Because of this, the threads are torn and holes are formed. Increase the fan speed on the last layers. nine0003

Few top layers

The top of the print may be too thin and deform as a result. Check slicer settings. The number of upper layers is not recommended to be set less than 6.

Low percentage of filling

If the infill percentage is too low, then the top layer will simply have nothing to rely on. Increase the fill percentage in the slicer settings.

Model deformation

Some parts of the model seem to have melted in some places or on one side. The problem most often occurs when printing with PLA plastic. The defect appears due to the fact that the plastic does not have time to cool and deforms.


Insufficient airflow model

Turn the fans on to maximum. If their power is not enough (in some printers, the fan is located only on one side), you can put a regular desktop fan and direct it to the 3D printer table. nine0003

Small model

Small models are difficult to blow well. Try to print small pieces alongside larger ones, or place several identical models in different corners of the table. So the plastic will have more time to cool.

Layer offset

Layers shift along the x or y axis during printing.


Print head jam

Turn off the printer and try to move the extruder along the x and y axes with your hands. The extruder must move freely. If there are jams, check the mechanics of the printer. Bearing wear or the curvature of the shafts may be to blame. nine0003

Electronics overheating

Sometimes electronics problems can be to blame for misaligned layers. The most common cause is overheating of the drivers or too low current exposed to them.

Table top is loose

This is most often seen in 3D printers with glass. During printing, the nozzle may hit the model and move the glass slightly. Before printing, check if the glass or other printing surface is well fixed on the heating table. nine0003

Skip layers

Small holes are visible on the print, or the shell of the model is not continuous.


Teflon tube deformed

There are 2 types of thermal barriers - all-metal and with a Teflon tube. If overheated, the Teflon tube may deform. Plastic will pass through it, but in a smaller amount.

Low extruder temperature or high print speed

If the extruder is not heated enough, then the plastic will not be liquid enough and simply will not have time to be forced through the nozzle. The higher the print speed, the higher the extruder temperature should be.

Sometimes the outer walls print well, but the infill is “torn”. In this case, slow down the infill print speed in the slicer.

Model bundle

Cracks form on the surface of the printout during or after printing. Cracks can be large or very small. Most often, this problem occurs with plastics with a high percentage of shrinkage - ABS or Nylon. nine0003


Sudden temperature difference (if model delaminates during printing)

With a sharp temperature difference (for example, a draft), part of the model cools down faster. This leads to uneven shrinkage and incorrect distribution of internal stress. For plastics with low shrinkage, this is not critical. But if the shrinkage percentage is more than a few percent, the model may burst in layers.

For printing with such plastics, it is recommended to use a printer with a closed housing. If this is not possible, try to avoid drafts and sudden temperature changes in the room where the 3D printer prints as much as possible. nine0003

Print temperature

Due to too low printing temperatures, the layers may not “stick” well to each other. Raise the print temperature in the slicer settings.

Hardening (if the model cracks after printing)

Sometimes cracks appear on the model a few days after printing. This is due to uneven distribution of internal stress after cooling. You can try to “harden” the finished product. nine0003

For hardening, the model is placed, for example, in an oven, and heated to the softening temperature of the plastic. After that, the heating is turned off and the oven is left to cool slowly with the model inside. Due to this, the stress inside the print is distributed more evenly. But accuracy is very important in this method - if you make a little mistake with the temperature, the finished product can “float”.

Ringing

In places where the extruder changed direction, ripples are visible. Most often it looks like a shadow around the “sharp” protruding elements of the model. nine0003


Mechanical problems

Sometimes the problem occurs due to extruder play. Check if the extruder mount to the rails is loose. Be sure to check the tension of all belts.

High print speed or high accelerations

Moving the extruder too fast can cause vibrations that cause ripples on the wall of the model. The lighter the weight of the extruder, the less noticeable the ripples will be. To get rid of ringing, simply reduce the print speed in the slicer settings. nine0003

Slits for thin-walled models (not solid shell)

The thin wall of the model is not solid, but consists of two thin walls with a narrow gap between them. This problem is often faced by fans of printing "cutting" for baking.

Left model with wall defect, right without

Wall thickness and nozzle diameter mismatch

If the wall thickness is 1 mm, and the nozzle diameter is 0. 4, it turns out that for a solid wall, 2 nozzle passes are few, and 3 are already many. The result will depend on the slicer algorithm, but most often you will get 2 walls with a thin slot in the middle (the slicer cannot change the wall thickness). The solution to the problem may be a slight refinement of the 3D model or the use of a different slicer. nine0003

Algorithms for calculating 3D models are constantly being improved and refined, and now this problem is less common.


When modeling, take into account not only the thickness of the nozzle, but also the percentage of “overlapping” of lines on each other. If you have a nozzle with a diameter of 0.4 - make the wall in your model not 0.8, but 0.7 - 0.75.

Wrong model geometry

When instead of a circle you get an oval, and instead of a square you get a semblance of a rhombus. nine0003


The main reason is malfunctions in the mechanics of the printer. Be sure to check:

Belts

Check belt tension in x and y. Belts stretch over time and may need to be tightened or replaced. Each 3D printer has its own way of tightening the belt. If the belts are slightly stretched, you can tighten them with the help of a "spring".

Loose pulleys, etc.

Check if all bolts and nuts are tight. Are there backlashes. Pay special attention to tightening the pulleys located on the motors along the x and y axes.


Sagging of some parts of the model

Some parts are not printed, broken, or instead of a neat surface, a swollen plastic snot is obtained.


No support for overhangs

A 3D printer cannot print in the air, so if there are overhanging elements in the model, you need to set supports - supports. The slicer can set the necessary support itself, you need to check the appropriate box in the settings. nine0003


When printing with soluble support, you can set the gap between the model and support - 0. This will make the surface smoother. If the support material and the model are the same, you need to add a small gap. Otherwise, it will be difficult to separate the support from the model.

Split model

Sometimes the supports can take more plastic than the model. In this case, to save material and time, it will be more convenient to cut the model. If you have more than one 3D printer, then the model will print several times faster. nine0003

When cutting the model, you can leave grooves or mortgages so that the pieces of the model are connected without displacement.


Totals

In this article, we talked about the most popular 3D printing defects and how to solve them. Don't be intimidated by such a long list. Some problems are rare and you are unlikely to encounter them.

There is a list of problems that arise due to the design features of a 3D printer, so try to choose a printer that suits your needs. To do this, you need to understand what products and what material you need. nine0003

Problems associated with printing algorithms are quickly eliminated by software developers.

Do not be afraid of possible difficulties and each print will be successful.


(There is a solution) How to achieve dimensional accuracy of printed parts

desktop-printer print-preparation

What precautions can be taken when designing parts that must match either external objects or other printed parts to ensure that the final 3D print is dimensionally accurate and conforms to another object? nine0003

As far as I know, there are at least two options for accounting for inaccuracy and printer shrinkage:

  • Adjust the space around the seams in the CAD model
  • Adjust size offsets in slicer software

Are there good workflows that can be used to accurately design and print 3D models without trial and error?

@Tormod Haugene, 👍17