Raw materials for 3d printers

• Plastic is still the most popular material used for 3D printing.
• As the 3D-printing market value increases, the list of what materials can be used also grows.
• Raw materials such as metal, graphite, and carbon fiber are commonly used for 3D printing, though at-home use is mostly limited to PLA for now.

Ice cream. Molecules for medicine. Even human skin. The list of what materials are used in 3D printing grows longer—and much more interesting—by the day. And expanding it is a multibillion-dollar material arms race right now.

A recently released 3D-printing market study found that the worldwide market for 3D-printing products was valued at $12. 6 billion in 2020 and was expected to grow to $37.2 billion by 2036. That means a huge increase in the materials those machines use.

What Is The Most Common Material Used for 3D Printing?

Plastic still reigns supreme in the 3D printing. According to a Grand View Research report, the market size for 3D printing plastics globally was valued at $638.7 million in 2020 and was expected to grow to $2.83 billion by 2027.

This material isn’t just your “everyday” plastic. Two types of plastic are most commonly used in 3D printing:

• PLA: Poly Lactic Acid (PLA) is the most popular 3D-printing material. It’s a biodegradable plastic made from renewables such as cornstarch. Its low melting point makes it easy to use at home.
• ABS: Acrylonitrile butadiene styrene (ABS) is best suited for parts that require strength and flexibility, like car components or household appliances. It’s also known for its low cost.

But it doesn’t stop there in the 3D-printing materials world.

1. Metal

Used for: Ready-to-install parts, finished products, prototypes

If there is a runner-up to plastic, it would be metal. Direct metal laser sintering (DMLS) is the technique and, unlike printing plastics, it can be used to make either a finished industrial product or a prototype. The aviation industry is already an early proponent and consumer of DMLS printing to streamline operations and manufacture ready-to-install parts. There are even already mass-market DMLS printers for creating 3D-printed jewelry.

The growth and popularity of 3D printing metals holds the potential to manufacture and create more effective machine parts that currently cannot be mass-produced onsite. This could lead to better conductors, tensile strength, and other attributes of laboratory metals than “mined-and-refined” metals such as steel and copper.

In the aerospace industry, the materials question is largely answered, and creating volume of parts is the Holy Grail. GE Aviation began printing fuel nozzles for its LEAP jet engine in 2016, ramping up to 30,000 parts in less than three years and printing its 100,000th nozzle in 2021. The LEAP’s successor, the RISE, will also incorporate 3D-printed parts.

Used for: Electronics, lighting

Australian-listed graphite and nickel miner Kibaran Resources has partnered with 3D-printing company 3D Group to share development costs on a research-and-development venture called 3D Graphtech Industries.

The partnership is pursuing patents to investigate 3D printing graphite and graphene, a pure form of carbon first created in a laboratory in 2004. Graphene conducts electricity better and is stronger, easier to insulate, and lighter than other conductors on the market today. It outperforms even the best conductors several times over. Because it must be created in a lab, it is a good case study for just what kind of mass production of metals additive manufacturing can accomplish.

Materials for research and development are sourced from Kibaran’s Tanzanian mines, where graphite with high crystallinity and a purity of 99.9% carbon has been found. This is incredibly well-suited to the production of graphene.

The semiconductor industry is interested in producing large quantities of graphene, as well. For example, IBM found a way to use it for LED lighting in 2014. The ability to 3D print sheets of material for use in LEDs could seriously cut lighting production costs.

Used for: Bearings, parts, electrical cable installation

Related to graphite, carbon fiber (which undergoes an oxidation process that stretches the polymer) can be added to the more traditional plastic to create a composite that can be as strong as steel but less intensive to use than aluminum, says Markforged. The company’s large-format 3D printers are designed to print stronger parts more quickly and at significantly lower costs.

Meanwhile, startup Impossible Objects has also been exploring carbon fiber, as well as glass, Kevlar, and fiberglass. The company’s printer can also work with PEEK (polyether ether ketone) thermoplastic polymers, which are typically used for bearings, piston parts, and electrical cable installation.

New 3D Printing Materials

The 3D-printing industry is experimenting with a wide variety of innovative, novel approaches such a bio-based resins made from corn and soybean oil, powders, nitinol, and even paper.

As the list of materials grows, what does this mean for the actual hardware? Right now, on the consumer level, plastic is about as good as it gets. For example, the $1,399 Dremel 3D40 Flex is limited to PLA.

Today, several printers are focused entirely on DMLS, including the 3DSystems DMP Flex 350 and several models from Stratasys, but these currently cost upward of $100,000 each because DMLS printers burn much hotter than their plastic counterparts, as the powders and metals they create have higher melting points. Stronger housings and more powerful industrial smelting tools increase their costs significantly.

Although many 3D-printer manufacturers are offering metal 3D-printing services, it will be some time before the economies of scale that helped bring down the cost of plastic 3D printing affect the DMLS market. And 3D-printing systems with graphite/carbon fiber are just now starting to gain traction in the marketplace.

The diversity of applications that industries are exploring for 3D printing makes for an exciting but tumultuous time. From jet parts to lighting to rapid prototyping, the new (and “old”) 3D printing materials will deliver even more opportunities for how and what industries print.

This article has been updated. It was originally published in November 2014.

About the Author

Jeff Yoders has covered IT, CAD, and BIM for Building Design + Construction, Structural Engineer, and CE News magazines. He has won six American Society of Business Publications Editors awards and was part of the reporting team for the 2012 Jesse H. Neal Award for best subject-related series of stories.

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What Materials Are Used in the 3D Printing Process?

The materials used for 3D printing are as diverse as the products that result from the process. As such, 3D printing is flexible enough to allow manufacturers to determine the shape, texture and strength of a product. Best of all, these qualities can be achieved with far fewer steps than what is typically required in traditional means of production. Moreover, these products can be made with various types of 3D printing materials.

In order for a 3D print to be realized in the form of a finished product, a detailed image of the design in question must first be submitted to the printer. The details are rendered in standard triangle language (STL), which conveys the intricacies and dimensions of a given design and allows a computerized 3D printer to see a design from all sides and angles.

Basically, an STL design is the equivalent of multiple flat designs in one computerized file.

The industry for 3D printing is expected to surpass the 10-figure mark in the near future and plastic is set to be the main material to drive this market. As concluded recently in a SmarTech Markets Publishing study, the market for 3D printing is likely to exceed $1.4 billion before 2020. With an ongoing market expansion, the industry has sought new ways to yield plastics, including the use of organic ingredients like soybean oil and corn. Consequently, plastics are set to become the most environmentally friendly option in 3D printing.

Plastic

Out of all the raw materials for 3D printing in use today, plastic is the most common. Plastic is one of the most diverse materials for 3D-printed toys and household fixtures. Products made with this technique include desk utensils, vases and action figures. Available in transparent form as well as bright colors — of which red and lime green are particularly popular — plastic filaments are sold on spools and can have either a matte or shiny texture.

With its firmness, flexibility, smoothness and bright range of color options, the appeal of plastic is easy to understand. As a relatively affordable option, plastic is generally light on the pocketbooks of creators and consumers alike.

Plastic products are generally made with FDM printers, in which thermoplastic filaments are melted and molded into shape, layer by layer. The types of plastic used in this process are usually made from one of the following materials:

• Polyastic acid (PLA): One of the eco-friendliest options for 3D printers, polyastic acid is sourced from natural products like sugar cane and corn starch and is therefore biodegradable. Available in soft and hard forms, plastics made from polyastic acid are expected to dominate the 3D printing industry in the coming years. Hard PLA is the stronger and therefore more ideal material for a broader range of products.
• Acrylonitrile butadiene styrene (ABS): Valued for its strength and safety, ABS is a popular option for home-based 3D printers. Alternately referred to as “LEGO plastic,” the material consists of pasta-like filaments that give ABS its firmness and flexibility. ABS is available in various colors that make the material suitable for products like stickers and toys. Increasingly popular among craftspeople, ABC is also used to make jewelry and vases.
• Polyvinyl Alcohol Plastic (PVA): Used in low-end home printers, PVA is a suitable plastic for support materials of the dissolvable variety. Though not suitable for products that require high strength, PVA can be a low-cost option for temporary-use items.
• Polycarbonate (PC): Less frequently used than the aforementioned plastic types, polycarbonate only works in 3D printers that feature nozzle designs and that operate at high temperatures. Among other things, polycarbonate is used to make low-cost plastic fasteners and molding trays.

Plastic items made in 3D printers come in a variety of shapes and consistencies, from flat and round to grooved and meshed. A quick search of Google images will show a novel range of 3D-printed plastic products such as mesh bracelets, cog wheels and Incredible Hulk action figures. For the home craftsperson, polycarbonate spools can now be purchased in bright colors at most supply stores.

Powders

Today’s more state-of-the-art 3D printers use powdered materials to construct products. Inside the printer, the powder is melted and distributed in layers until the desired thickness, texture and patterns are made. The powders can come from various sources and materials, but the most common are:

• Polyamide (Nylon): With its strength and flexibility, polyamide allows for high levels of detail on a 3D-printed product. The material is especially suited for joining pieces and interlocking parts in a 3D-printed model. Polyamide is used to print everything from fasteners and handles to toy cars and figures.
• Alumide: Comprised of a mix of polyamide and gray aluminum, alumide powder makes for some of the strongest 3D-printed models. Recognized by its grainy and sandy appearance, the powder is reliable for industrial models and prototypes.

In powder form, materials like steel, copper and other types of metal are easier to transport and mold into desired shapes. As with the various types of plastic used in 3D printing, metal powder must be heated to the point where it can be distributed layer-by-layer to form a completed shape.

Resins

One of the more limiting and therefore less-used materials in 3D printing is resin. Compared to other 3D-applicable materials, resin offers limited flexibility and strength. Made of liquid polymer, resin reaches its end state with exposure to UV light. Resin is generally found in black, white and transparent varieties, but certain printed items have also been produced in orange, red, blue and green.

The material comes in the following three categories:

• High-detail resins: Generally used for small models that require intricate detail. For example, four-inch figurines with complex wardrobe and facial details are often printed with this grade of resin.
• Paintable resin: Sometimes used in smooth-surface 3D prints, resins in this class are noted for their aesthetic appeal. Figurines with rendered facial details, such as fairies, are often made of paintable resin.
• Transparent resin: This is the strongest class of resin and therefore the most suitable for a range of 3D-printed products. Often used for models that must be smother to the touch and transparent in appearance.

Transparent resins of clear and colored varieties are used to make figurines, chess pieces, rings and small household accessories and fixtures.

Metal

The second-most-popular material in the industry of 3D printing is metal, which is used through a process known as direct metal laser sintering or DMLS. This technique has already been embraced by manufacturers of air-travel equipment who have used metal 3D printing to speed up and simplify the construction of component parts.

DMLS printers have also caught on with makers of jewelry products, which can be produced much faster and in larger quantities — all without the long hours of painstakingly detailed work — with 3D printing.

Metal can produce a stronger and arguably more diverse array of everyday items. Jewelers have used steel and copper to produce engraved bracelets on 3D printers. One of the main advantages of this process is that the engraving work is handled by the printer. As such, bracelets can be finished by the box-load in just a few mechanically programmed steps that do not involve the hands-on labor that engraving work once required.

The technology for metal-based 3D printing is also opening doors for machine manufacturers to ultimately use DMLS to produce at speeds and volumes that would be impossible with current assembly equipment. Supporters of these developments believe 3D printing would allow machine-makers to produce metal parts with strength superior to conventional parts that consist of refined metals.

In the meantime, the use of 3D parts is taking flight in the aerospace industry. In what has been the most ambitious push of its kind, GE Aviation plans to print engine injectors at an annual rate of 35,000 units by 2020.

The range of metals that are applicable to the DMLS technique is just as diverse as the various 3D printer plastic types:

• Stainless-steel: Ideal for printing out utensils, cookware and other items that could ultimately come into contact with water.
• Bronze: Can be used to make vases and other fixtures.
• Gold: Ideal for printed rings, earrings, bracelets and necklaces.
• Nickel: Suitable for the printing of coins.
• Aluminum: Ideal for thin metal objects.
• Titanium: The preferred choice for strong, solid fixtures.

In the printing process, metal is utilized in dust form. The metal dust is fired to attain its hardness. This allows printers to bypass casting and make direct use of metal dust in the formation of metal parts. Once the printing has completed, these parts can then be electro-polished and released to the market.

Metal dust is most often used to print prototypes of metal instruments, but it has also been used to produce finished, marketable products such as jewelry. Powderized metal has even been used to make medical devices.

When metal dust is used for 3D printing, the process allows for a reduced number of parts in the finished product. For example, 3D printers have produced rocket injectors that consist of just two parts, whereas a similar device welded in the traditional manner will typically consist of more than 100 individual pieces.

Carbon Fiber

Composites such as carbon fiber are used in 3D printers as a top-coat over plastic materials. The purpose is to make the plastic stronger. The combination of carbon fiber over plastic has been used in the 3D printing industry as a fast, convenient alternative to metal. In the future, 3D carbon fiber printing is expected to replace the much slower process of carbon-fiber layup.

With the use of conductive carbomorph, manufacturers can reduce the number of steps required to assemble electromechanical devices.

Graphite and Graphene

Graphene has become a popular choice for 3D printing because of its strength and conductivity. The material is ideal for device parts that need to be flexible, such as touchscreens. Graphene is also used for solar panels and building parts. Proponents of the graphene option claim it is one of the most flexible of 3D-applicable materials.

The use of graphene in printing received its largest boost through a partnership between the 3D Group and Kibaran Resources, an Australian mining company. The pure carbon, which was first discovered in 2004, has proven to be the most electrically conductive material in laboratory tests. Graphene is light yet strong, which makes it the suitable material for a range of products.

Nitinol

As a common material in medical implants, nitinol is valued in the 3D printing world for its super-elasticity. Made from a mixture of nickel and titanium, nitinol can bend to considerable degrees without breaking. Even if folded in half, the material can be restored to its original shape. As such, nitinol is one of the strongest materials with flexible qualities. For the production of medical products, nitinol allows printers to accomplish things that would otherwise be impossible.

Paper

Designs can be printed on paper with 3D technology to achieve a far more realistic prototype than a flat illustration. When a design is presented for approval, the 3D-printed model allows the presenter to convey the essence of the design with greater detail and accuracy. This makes the presentation far more compelling, as it gives a more vivid sense of the engineering realities should the design be taken to fruition.

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FDM/FFF Consumables

FFF technology has many advantages, including the relative simplicity of the design of printers and the affordability of both devices and consumables. Moreover, the range of materials is perhaps the widest among all available technologies. As a rule, thermoplastics are used for printing, but there are exceptions - composite materials containing various additives, but based, again, on thermoplastics. In this section, we will try to talk about the most widely used materials in more detail, starting with the most popular types.

• 1 Polylactide (PLA, PLA)
• 2 Acrylonitrile butadiene styrene (ABS)
• 3 Polyvinyl alcohol (PVA)
• 4 Nylon
• 5 Polycarbonate (PC)
• 6 High density polyethylene (HDPE)
• 7 Polypropylene (PP, PP)
• 8 Polycaprolactone (PCL)
• 9 Polyphenylsulfone (PPSU)
• 10 Polymethyl methacrylate (Acrylic, plexiglass, acrylic, PMMA)
• 11 Polyethylene terephthalate (PET, PET)
• 12 High impact polystyrene (HIPS)
• 13 Wood Simulators (LAYWOO-D3, BambooFill)
• 14 Sandstone Simulators (Laybrick)
• 15 Metal Simulators (BronzeFill)

Polylactide (PLA, PLA)

Polylactide is one of the most widely used thermoplastics due to several factors. Let's start with the fact that PLA is known for its environmental friendliness. This material is a lactic acid polymer, which makes PLA a completely biodegradable material. The raw materials for the production of polylactide are corn and sugar cane. At the same time, the environmental friendliness of polylactide causes its fragility. Plastic easily absorbs water and is relatively soft. As a rule, PLA models are not intended for functional use, but serve as designer models, souvenirs and toys. Few practical industrial applications include the production of food packaging, drug containers and surgical sutures, as well as use in bearings that do not carry high mechanical loads (for example, in modeling), which is possible due to the material's excellent slip coefficient.

One of the most important factors for 3D printing applications is the low melting temperature of only 170-180°C, which contributes to relatively low power consumption and the use of inexpensive brass and aluminum nozzles. As a rule, extrusion is carried out at 160-170°C. At the same time, PLA solidifies quite slowly (glass transition temperature is about 50°C), which should be taken into account when choosing a 3D printer. The best option is a device with an open case, a heated work platform (to avoid deformation of large models) and, preferably, additional fans to cool the fresh layers of the model.

PLA has low shrinkage, i.e. loss of volume on cooling, which helps prevent warping. However, shrinkage has a cumulative effect as the dimensions of printed models increase. In the latter case, the build platform may need to be heated to evenly cool the printed objects.

The cost of PLA is relatively low, which adds to the popularity of this material.

Acrylonitrile Butadiene Styrene (ABS)

ABS is perhaps the most popular thermoplastic used in 3D printing, but not the most common. This contradiction is explained by certain technical difficulties that arise when printing ABS. The desire of craftsmen to use ABS is determined by the excellent mechanical properties, durability and low cost of this material. In the industry, ABS plastic is already widely used: the production of car parts, cases of various devices, containers, souvenirs, various household accessories, etc.

ABS plastic is resistant to moisture, acids and oil, has a fairly high temperature resistance - from 90°C to 110°C. Unfortunately, some types of material are destroyed by direct sunlight, which somewhat limits the application. At the same time, ABS plastic is easy to paint, which allows you to apply protective coatings on non-mechanical elements.

Despite a relatively high glass transition temperature of around 100°C, ABS has a relatively low melting point. Actually, due to the amorphous nature of the material, ABS does not have a melting point, as such, but 180 ° C is considered an acceptable temperature for extrusion, which is on the same level as the above-described PLA. The lower temperature spread between extrusion and glass transition allows ABS to cure faster than PLA.

The main disadvantage of ABS plastic can be considered a high degree of shrinkage during cooling - the material can lose up to 0.8% of its volume. This effect can lead to significant deformations of the model, twisting of the first layers and cracking. To combat these unpleasant phenomena, two main solutions are used. First, heated work platforms are used to help reduce the temperature gradient between the lower and upper layers of the model. Secondly, ABS 3D printers often use closed housings and control of the background temperature of the working chamber. This makes it possible to maintain the temperature of the applied layers at a level just below the glass transition threshold, reducing the degree of shrinkage. Full cooling is carried out after receiving the finished model.

The relatively low stickiness of ABS may require additional bonding aids such as adhesive tape, polyimide film, or applying an acetone solution of the ABS to the platform just prior to printing. For more information on how to avoid warping, see How to Avoid Warping 3D Printed Models.

While ABS is not a health hazard at room temperature, heated plastic releases acrylonitrile fumes, a poisonous compound that can irritate mucous membranes and cause poisoning. Although the amount of Acrylonitrate produced in small scale printing is negligible, it is recommended that you print in a well ventilated area or use an exhaust hood. It is not recommended to use ABS plastic for the production of food containers and utensils (especially for storing hot food or alcoholic beverages) or toys for small children.

The good solubility of ABS in acetone is very useful as it allows large models to be produced piece by piece and glued together, greatly expanding the capabilities of inexpensive desktop printers.

Polyvinyl alcohol (PVA)

Polyvinyl alcohol is a material with unique properties and special applications. The main feature of PVA is its water solubility. 3D printers equipped with dual extruders have the ability to print models with PVA support structures. Upon completion of printing, the supports can be dissolved in water, leaving a finished model that does not require mechanical or chemical roughening. Similarly, PVA can be used to create water-soluble master patterns for molds and molds themselves.

The mechanical properties of PVA are quite interesting. At low humidity, plastic has high tensile strength. With increasing humidity, strength decreases, but elasticity increases. The extrusion temperature is 160-175°C, which allows the use of PVA in printers designed for printing with ABS and PLA plastics.

Since the material easily absorbs moisture, it is recommended to store PVA plastic in dry packaging and, if necessary, dry before use. Drying can be done in a pottery kiln or an ordinary oven. As a rule, drying of standard coils takes 6-8 hours at a temperature of 60-80°C. Exceeding 220°C will cause the plastic to decompose, which should be taken into account when printing.

Nylon

Nylon is attractive due to its high wear resistance and low coefficient of friction. Thus, nylon is often used to coat friction parts, which improves their performance and often allows them to function without lubrication. Following the widespread use of nylon in industry, additive manufacturing has also become interested in the material. Attempts to print with nylon have been made almost since the early days of FDM/FFF technology.

In reality, there are several types of nylon produced by different methods and with slightly different characteristics. The most famous is nylon-66, created by the American company DuPont in 1935. The second most popular option is nylon-6, developed by BASF to circumvent the DuPont patent. These two options are very similar. In terms of 3D printing, the main difference is the melting point: Nylon-6 melts at 220°C, while Nylon-66 melts at 265°C.

Many hobbyists prefer to use commercially available nylon threads such as trimmer wire. The diameter of such materials often corresponds to the diameter of standard FFF materials, which makes their use tempting. At the same time, these products are usually not pure nylon. In the case of trimmer rods, the material consists of nylon and fiberglass for an optimal combination of flexibility and rigidity.

Fiberglass has a high melting point and therefore printing with these materials is prone to high nozzle wear and plugging.

Recently there have been attempts to commercially develop nylon-based printing materials specifically for FDM/FFF applications, including Nylon-PA6 and Taulman 680. These grades are extrudable at 230-260°C.

Since nylon easily absorbs moisture, store consumables in vacuum packaging or at least in a container with water-absorbing materials. A sign of excessively damp media will be steam escaping from the nozzle during printing, which is not dangerous, but may degrade the quality of the model.

When printing with nylon, it is not recommended to use a polyimide desktop coating as the two materials fuse together. As a coating, you can use adhesive tape with wax impregnation (masking tape). The use of a heated bed will help reduce the possibility of deformation of the model, similar to printing with ABS plastic. Due to the low coefficient of friction of nylon, extruders with studded feeders should be used.

The nylon layers have excellent adhesion, minimizing the chance of delamination.

Nylon is difficult to bond, making it difficult to print large multi-piece models. Alternatively, fusion of parts is possible.

Because nylon can release toxic fumes when heated, we recommend that you print in a well-ventilated area or use an exhaust fan.

Polycarbonate (PC)

Polycarbonates are attractive due to their high strength and toughness, as well as resistance to high and low temperatures.

The potential health risk of printing is worth noting: the toxic and potentially carcinogenic compound bisphenol A is often used as a raw material. .

The extrusion temperature depends on the printing speed to avoid cracking, but the minimum temperature at 30mm/s can be considered as 265°C. When printing, the use of polyimide film is recommended for better adhesion to the desktop surface. The high susceptibility of polycarbonate to deformation requires the use of a heated platform and, if possible, a closed housing with heating of the working chamber.

Polycarbonate is highly hygroscopic (easily absorbs moisture), which requires storage in dry conditions to avoid the formation of bubbles in the applied layers. For extended printing in humid climates, even the print spool may need to be stored in a moisture-proof container.

High Density Polyethylene (HDPE)

Arguably the most common plastic in the world, polyethylene is relatively rare among 3D printed materials. The reason for this is the difficulty in layer-by-layer manufacturing of models.

Polyethylene melts easily (130-145°C) and hardens quickly (100-120°C), as a result of which the applied layers often do not have time to set. In addition, polyethylene is characterized by high shrinkage, which provokes the twisting of the first layers and the deformation of the models as a whole during uneven solidification. Printing with polyethylene requires the use of a heated platform and a working chamber with accurate temperature control to slow down the cooling of the applied layers. In addition, you will need to print at high speed.

Difficulties in use are more than offset by the cheapness and availability of this material. Recently, several devices have been developed for processing plastic waste from HDPE (bottles, food packaging, etc.) into standard filaments for printing on FDM/FFF printers. Examples are FilaBot and RecycleBot. Due to the simplicity of design, RecycleBot devices are often assembled by 3D craftsmen.

Melting polyethylene releases harmful vapors, so it is recommended to print in well-ventilated areas.

Polypropylene (PP, PP)

Polypropylene is a widely used plastic used in the manufacture of packaging materials, utensils, syringes, pipes, etc. The material has a low specific gravity, is non-toxic, has good chemical resistance, is resistant to moisture and wear, and cheap enough. Among the disadvantages of polypropylene, one can note the vulnerability to temperatures below -5 ° C and to direct sunlight.

The main difficulty in printing with polypropylene is the high shrinkage of the material during cooling - up to 2.4%. For comparison, the shrinkage of the popular but already problematic ABS plastic reaches 0.8%. Although polypropylene adheres well to cold surfaces, it is recommended to print on a heated platform to avoid deformation of models. The minimum recommended extrusion temperature is 220°C.

Polypropylene printing filaments are sold by Orbi-Tech, German RepRap, Qingdao TSD Plastic. Stratasys has developed a polypropylene simulant optimized for 3D printing called Endur.

Polycaprolactone (PCL)

Polycaprolactone (aka Hand Moldable Plastic, Mold-Your-Own Grips, InstaMorph, Shapelock, Friendly Plastic, Polymorph, Polymorphus, Ecoformax) - biodegradable polyester, characterized by an extremely low melting point of about 60 ° C . In practice, this property creates certain problems in 3D printing, since not all 3D printers can be configured to work at such low temperatures. Heating polycaprolactone to the usual extrusion temperatures (about 200°C) causes a loss of mechanical properties and may lead to breakage of the extruder.

Polycaprolactone is non-toxic, making it suitable for use in the medical industry, and biodegradable. When ingested, polycaprolactone breaks down, which makes printing with this material safe. Due to the low melting point, there is no danger of burns when touching fresh models. The high plasticity of the material makes it possible to reuse.

Polycaprolactone is of little use for creating functional mechanical models due to its viscosity (glass transition temperature is -60°C) and low heat resistance (melting point is 60°C). On the other hand, this material is perfect for the production of mock-ups and food containers.

The material sticks easily to the surface of even a cold working table and is easy to paint.

Polyphenylsulfone (PPSU)

Polyphenylsulfone is a high strength thermoplastic used extensively in the aviation industry. The material has excellent chemical and thermal stability and practically does not burn. Polyphenylsulfone is biologically inert, which makes it possible to use this material for the production of tableware and food containers. Operating temperature range is -50°С - 180°С. Plastic is resistant to solvents and fuels and lubricants.

For all its merits, polyphenylsulfone is rarely used in 3D printing due to its high melting point, reaching 370°C. Such extrusion temperatures are beyond the power of most desktop printers, although printing is theoretically possible using ceramic nozzles. Currently, the only active user of the material is Stratasys, which offers industrial Fortus installations.

Polymethyl methacrylate (Acrylic, plexiglass, acrylic, PMMA)

Polymethyl methacrylate is a well-known organic glass. The material is durable, moisture resistant, environmentally friendly, easy to glue, plastic enough and resistant to direct sunlight.

Unfortunately, acrylic is not suitable for FDM/FFF printing for a number of reasons. Acrylic is poorly stored in the form of spools of thread, as constant mechanical stress leads to the gradual destruction of the material. To avoid bubbles, the print resolution must be high, with a precision almost impossible for home printers. Acrylic's rapid curing requires strict environmental control of the working chamber and high print speeds. Again, the print speeds of FDM/FFF printers are inversely related to print resolution, which exacerbates the problem.

However, attempts are being made to print with acrylic, and some of them are producing relatively positive results. However, when creating sufficiently strong models, it is not yet possible to avoid the formation of bubbles and achieve the usual transparency of the material. At the moment, the best results with acrylic are shown by another printing technology - multi-jet modeling (MJM) from 3D Systems. In this case, a photopolymer version of acrylic is used. Stratasys has also made significant progress using its own photopolymer acrylic simulant VeroClear on Objet Eden printers. It is hoped that the high demand for acrylic will lead to the emergence of composite materials based on polymethyl methacrylate, designed specifically for FDM/FFF printing.

Polyethylene terephthalate (PET, PET)

Polyethylene terephthalate - this complex name hides a material used for the production of plastic bottles and other food and medical containers.

The material has a high chemical resistance to acids, alkalis and organic solvents. The physical properties of PET are also impressive with high wear resistance and tolerance to a wide temperature range from -40°C to 75°C. Among other things, the material is easily machined.

Printing with PET is somewhat problematic due to the relatively high melting point of up to 260°C and significant cooling shrinkage of up to 2%. Using PET as a consumable requires approximately the same conditions as printing with ABS.

Achieving transparency of models requires rapid cooling to pass the glass transition threshold of 70°C - 80°C.

The material has become the focus of interest for 3D craftsmen using used containers as raw materials for the home production of 3D printing consumables. Recycling devices such as FilaBot or RecycleBot are used to make threads.

High impact polystyrene (HIPS)

High impact polystyrene is widely used in industry for the production of various household products, building materials, disposable tableware, toys, medical instruments, etc.

When 3D printed, polystyrene exhibits physical properties very similar to the popular ABS plastic, making it an increasingly popular material among 3D crafters. The most attractive feature of polystyrene is the difference from ABS in terms of chemical properties: polystyrene is quite easily amenable to the organic solvent Limonen. Since Limonene has no effect on ABS plastic, it is possible to use polystyrene as a material for building soluble support structures, which is extremely useful when building complex, interlaced models with internal supports. Compared to the convenient, water-soluble polyvinyl alcohol (PVA) plastic, polystyrene compares favorably with relatively low cost and resistance to humid climates that make PVA difficult to work with.

It's worth bearing in mind that some ABS manufacturers mix slightly cheaper polystyrene into their consumables. Accordingly, models made from such materials can be dissolved in Limonene along with supporting structures.

When polystyrene is heated to extrusion temperature, toxic fumes can be released, so printing in a well-ventilated area is recommended.

Wood simulants (LAYWOO-D3, BambooFill)

LAYWOO-D3 is a recent development for printing wood-like models. The material consists of 40% natural wood chips of microscopic size and 60% binder polymer. The LAYWOO-D3 is very easy to handle, being virtually warp-free and does not require the use of a heated platform. According to the manufacturers, the polymer is non-toxic and completely safe.

The unique material properties allow for different visual results when printing with different nozzle temperatures. The operating temperature range is 180°C-250°C. As the extrusion temperature increases, the shade of the material becomes progressively darker, allowing it to simulate different types of wood or annual rings.

Finished models are excellent for mechanical processing - grinding, drilling, etc. In addition, the products are easily painted, and unpainted models even have a characteristic woody smell.

Unfortunately, the cost of the material is almost four times higher than the price of popular materials such as PLA and ABS plastics. As popularity is projected to grow, the material should become more accessible.

Alternative materials are currently being developed and tested, such as BambooFill from the Dutch company ColorFabb.

Sandstone simulants (Laybrick)

Composite material from the inventor Kai Parti, responsible for the revolutionary wood simulant LAYWOO-D3. This time, Kai set his sights on sandstone imitation, using a tried and tested method of mixing a binder with a filler, in this case mineral.

Laybrick allows you to produce objects with different surface textures. At low extrusion temperatures of the order of 165°C-190°C, the finished products have a smooth surface. Increasing the printing temperature makes the material rougher, up to a high degree of resemblance to natural sandstone at extrusion temperatures above 210°C.

The material is easy to work with no need to heat the work platform, does not show significant deformation when shrinking and does not produce toxic fumes when heated. The only drawback can be considered a rather high cost of the material, which is largely due to limited production.

Metal Simulators (BronzeFill)

Metals have attracted additive manufacturing enthusiasts since the early days of 3D printing technology. Unfortunately, printing with pure metals and alloys causes a lot of difficulties that are insurmountable for most 3D printing methods. Fully functional metal products can only be produced using technologies such as SLS, DLMS or EBM, which require the use of industrial plants that cost hundreds of thousands of dollars. At the same time, metal imitators are successfully used in 3D inkjet printing (3DP), where products are formed from metal powders, the particles of which are held together by an applied binder material. In FDM/FFF printing, metal simulants are just emerging.

An interesting example is BronzeFill, which is actually a transparent PLA plastic filled with bronze microparticles. The material, currently in beta testing, must prove suitability for use in any printer designed to work with polylactide.

Finished products are easy to polish, achieving a high external resemblance to all-metal products. At the same time, it should be taken into account that the binding element of the material is thermoplastic, with appropriate mechanical and temperature limitations.

Go to the main page of the 3D Printing Encyclopedia

Types of Plastic for 3D Printer

Content

• • ABS
  • HIPS
  • PVA
  • Petg
  • SBS
  • 9000

Every year 3D printing becomes more popular and accessible. Previously, a 3D printer was more like a complex CNC machine, but now manufacturers are meeting users. Simplified and automated settings that many beginners drove into a stupor. Despite this, it can be difficult for a novice user to understand the variety of constantly appearing plastics for a 3D printer.

The choice of plastic for a 3D printer is very important, especially when the goal is to print a functional model with certain properties. It will be a shame if the printed gear breaks almost immediately, or the decorative model quickly loses its beauty.

It is important to understand whether the printer will be able to work with the selected plastic. Some materials (most often engineering) require certain conditions for successful printing.

First, decide which model you want to print. What properties should it have? Does the model need to be durable? Or is it a master model for further replication, in which the quality of the surface is important?

90% of 3D printers use 1.75 diameter filament. 3mm diameter is rare, but it is better to check in advance which size is used in your printer.

PLA

PLA (Polylactide) is the most popular and affordable 3D printer plastic. PLA is made from sugar cane, corn, or other natural raw materials. Therefore, it is considered a non-toxic, biodegradable material.

Extruder temperature - 190-220 degrees. Table heating is not needed, but if the printer's table has a "heater" for better adhesion, you can heat it up to 50-60 degrees. PLA is very easy to work with. The only requirement is to blow the model. There is practically no shrinkage in this material. When printed, it is practically odorless, and if it smells, it smells like burnt caramel.

Pros:

• Does not shrink. This makes it easy to build prefabricated or huge models without changing dimensions.

• There are no specific requirements for a 3D printer. Any working 3D printer will do. PLA doesn't need a heated table or a closed case.

• Non-toxic. Due to this, during printing it does not smell or has a barely perceptible aroma of burnt caramel.

• Diverse color palette.

Cons:

• PLA is poorly sanded and machined.

• It begins to deform already with a slight heating (about 50 degrees).

• Fragility. Compared to other materials, PLA is very brittle and breaks easily.

• Decomposes under the influence of ultraviolet radiation. Of course, it will not fall apart into dust, but it can become more brittle and fade.

PLA is perfect for making dimensional or composite models. For example, decorative interior items, prototyping, electronics cases, etc.

Recently, PLA+ has appeared on the market. It may differ from conventional PLA in improved performance. For example, more durable, with improved layer adhesion.

Dummy turbine


Decorative coasters


ABS

ABS (acrylonitrile butadiene styrene) is the second most popular plastic for 3D printing due to its properties, availability and low price.

Extruder temperature - 220-240 degrees. The temperature of the table is 80-100 degrees. For printing, a heated table is required at the printer. It is desirable to have a closed chamber, because ABS "does not like" drafts. Due to a sharp temperature drop, it can “unstick” from the table or crack in layers. ABS can smell bad when printing, so it is recommended to use the printer with a closed chamber and filters, or print in a well-ventilated area.

Pros:

• Good strength characteristics allow the production of functional prototypes from ABS.

• Simple mechanical and chemical processing. ABS is easy to sand and drill, and with an acetone bath you can achieve a perfectly smooth surface.

• It is currently the most inexpensive type of plastic for 3D printing.

• Large selection of colors and shades.

Cons:

• High shrinkage. Because of this, it can be problematic to manufacture overall products.

• Printing requires a heated bed and a closed chamber. Without this, the ABS may peel off the table or crack in layers.

• During the printing process, ABS can smell bad. Therefore, it is recommended that you print in a ventilated area or use the printer with a sealed chamber and filter.

ABS is an engineering plastic. It is suitable for the manufacture of simple functional products.

ABS after chemical treatment in an acetone bath


RU model made of ABS


ABS+ differs from conventional ABS in improved strength characteristics (elasticity, rigidity, hardness), less shrinkage and sometimes resistance to certain oils and solvents (eg gasoline).




HIPS

HIPS (high impact polystyrene) - originally conceived as a soluble support plastic for materials with high printing temperatures. For example for ABS or Nylon.

The extruder temperature is 230-260 degrees. The temperature of the table is 80-100 degrees. It is desirable to have a closed camera for a 3D printer.

Pros:

• Less shrinkage than ABS.

• Ease of machining.

• The matte surface looks very advantageous on decorative products.

• Food contact allowed (but be sure to check with a specific manufacturer for certificates)

Cons:

• For printing, you need a printer with a heated table and a closed chamber.

• More flexible and less durable than ABS. Because of this, it will not be possible to produce functional products.

• Small palette of colors.

Most often, HIPS is used for its intended purpose for printing on 2x extruder printers as a support for ABS. It dissolves perfectly (though not very quickly) in limonel.

Sometimes HIPS is used as an independent material. Products from it are not very durable, but this plastic is loved for easy post-processing. HIPS can be used for models that will subsequently come into contact with food (not hot).

Using HIPS as a Soluble Support

Decorative vase made of HIPS




PVA

PVA (polyvinyl alcohol) is a material that was developed as a water-soluble support for PLA.

Extruder temperature - 190-210. Table heating is not required. PVA is a slightly "capricious" material, it is not recommended to overheat it and print at high speeds.

PVA is very hygroscopic and dissolves in plain water. Therefore, it is only used as a support for PLA or other plastics with print temperatures close to PVA.

Soluble PVA Support





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PETG

PETG (polyethylene terephthalate) combines the best properties of PLA and ABS. It is easy to work with, it has a low percentage of shrinkage and excellent sintering of the layers.

Extruder temperature - 220-240 degrees. Table temperature - 80-100 degrees. During the printing process, the model must be well blown.

Pros:

• Excellent sinterability of layers.

• PETG is very strong and wear resistant. Good impact resistance.

• Virtually no smell when printing.

• Non-toxic.

• Little shrinkage.

Cons:

PETG is perfect for printing functional models. Due to its low shrinkage, it is often used to make large or composite models. Due to its low toxicity, PETG is often used for products that will come into contact with food.

Cookie cutters and patterned rolling pin


SBS

It is a highly transparent material. At the same time, it is durable and resilient. SBS is a low toxicity plastic. It can be used to print food contact models.

Extruder temperature - 230 -260 degrees. Table temperature - 60-100 degrees. You can print without the closed case on the printer.

Pros:

• slight shrinkage

• Transparency. After treatment with solvent, limonel or dichloromethane, beautiful transparent products with an almost smooth surface can be obtained.

• Easily processed mechanically or chemically.

• Allowed contact with food.

Cons:

SBS is excellent for translucent vases, children's toys and food containers. Or functional things that require transparency, such as custom turn signals for a motorcycle or car, lamps or bottle prototypes.

Vases are perfectly printed with a thick nozzle (0.7-0.8) in one pass (printing in 1 wall or spiral printing in a slicer).

Models of bottles after chemical treatment




Nylon

Nylon (polyamide) is considered the most durable material available for home 3D printing. In addition to good abrasion resistance and strength, it has a high slip coefficient.

Extruder temperature - 240-260 degrees. The temperature of the table is 80-100 degrees. Nylon is a very capricious and hygroscopic material - it is recommended to dry the coil with plastic before use. For printing, you need a printer with a heated table and a closed chamber, without this it will be difficult to print something larger than a small gear.

Pros:

• High strength and wear resistance.

• High slip factor.

• Heat resistance compared to other 3D printing plastics.

• High resistance to many solvents.

• Good for mechanical processing. Perfectly polished and drilled.

Cons:

Nylon is perfect for making wear-resistant parts - gears, functional models, etc. Sometimes nylon is used to print bushings.

Nylon gear

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Soft plastics

FLEX (TPU, TPE, TPC) is a material similar to silicone or rubber. It is flexible and elastic, but at the same time tear-resistant. For example, TPE is a rubbery plastic, while TPU is more rigid.

FLEX are printed at a temperature of 200-240 (depending on the material). A heated table is not required. On printers with direct material feed (feed mechanism on the print head), there are usually no problems with printing. On a bowden feeder (the feed mechanism is located on the body), printing with very soft plastics can be difficult. Usually it is necessary to additionally adjust the clamping of the bar. The main nuance is the very low print speeds - 20-40mm.

Pros:

Cons:

Depending on the type of FLEXa, the models can be flexible or rubber-like. This material, depending on its softness, can be used to print gaskets, insoles, belts, tracks or other models that require flexibility or softness.

FLEX belt


Trainers with flexible soles


Wheel for switchgear model

Decorative plastics

Decorative plastics are PLA plastics with various fillers (wood or metal shavings). Or with dyes selected to imitate different materials. Since the base of the plastic is PLA, it is very easy to print.

Extruder temperature - 200-220 degrees (depending on the manufacturer). A heated table is not required.

Pros:

Cons:

• Some fillers (eg clay) are abrasive. For such plastics, the standard brass nozzle cannot be used. Will have to buy a harder steel nozzle.

• Some decorative plastics can clog the small nozzle (0.4 or less). For them, you need to use a “thicker” nozzle.

Depending on the filler, different material properties are obtained. Plastics that use only dye do not require additional processing. Materials with "fillers" may sometimes require additional post-processing.

Plastics with metal fillers after printing must be processed with a metal brush. Then the Metal content will show through and the model will resemble a metal casting.

Plastics with metallic powder


These plastics are often used for printing key chains, decorative models and interior details.

If the plastic has a high content of wood dust, then it is recommended to use a larger nozzle diameter (0.5 or more), a smaller nozzle can quickly become clogged during printing.

Wood-filled plastic ground

Plastic key rings with copper dust

Engineering plastics

These are nylon-based plastics with fillers that improve strength, heat-resistant and other characteristics, help to achieve less shrinkage of the material. For example - carbon fiber, carbon fiber or fiberglass.

Extruder temperature - 240-300 degrees (depending on the manufacturer). Table temperature - 90-110 degrees. Since plastics are based on nylon, the requirements for printing are similar. This is a heated table and a closed printer case.

Pros:

• Hardness and strength.

• Low flammability or non-combustibility.

• High precision due to low shrinkage.

Cons:




3D printers use brass nozzles, some plastics can quickly “waste” it during printing. For such materials it is recommended to use steel nozzles.

These are highly specialized plastics used for a specific task, depending on the filler. For example, functional parts that do not lose their shape when heated, are resistant to many solvents, etc.

Functional carbon fiber composite prototype


Composite frame


Polycarbonate ashtray


Totals

This is of course not the whole list of materials for 3D printing. There are many highly specialized engineering and decorative plastics for specific tasks.

Manufacturers are constantly trying to replenish the range of materials for 3D printing. Already familiar materials are improved for more comfortable printing. There are many interesting decorative plastics imitating different materials - ceramics, clay, wood, metals.

And of course, the assortment of engineering plastics is constantly updated. Now there are many interesting materials for highly specialized tasks - for example, burnable plastic with a low ash content for subsequent casting in metal.

Burnout plastic

Before buying a coil, read the information on the website of the manufacturer or seller. There you can find some nuances of printing for a particular plastic. The manufacturer indicates the recommended temperature range on the box. Sometimes, for quality printing, it is recommended to print several tests to adjust the temperature settings, retract, etc.

Try to store the started coil in silica gel bags.

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